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4-(2,4-Dichloro­phen­yl)-5,5-dimethyl-2-(3-silatranyl­propyl­mino)-1,3,2-dioxa­phospho­rinane 2-oxide

In the title compound, C(20)H(31)Cl(2)N(2)O(6)PSi, the dioxaphospho­rinane ring adopts a cis conformation. The silatrane fragment forms a cage-like structure in which there exists an intra­molecular Si—N donor–acceptor bond. In the crystal, centrosymmetrically related mol­ecules are linked by pairs...

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Detalles Bibliográficos
Autores principales: Liu, Zhe-Rong, Tan, Xiao-Jing, Wang, De-Jian, Wang, Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238936/
https://www.ncbi.nlm.nih.gov/pubmed/22199785
http://dx.doi.org/10.1107/S1600536811044928
Descripción
Sumario:In the title compound, C(20)H(31)Cl(2)N(2)O(6)PSi, the dioxaphospho­rinane ring adopts a cis conformation. The silatrane fragment forms a cage-like structure in which there exists an intra­molecular Si—N donor–acceptor bond. In the crystal, centrosymmetrically related mol­ecules are linked by pairs of N—H⋯O hydrogen bonds into inversion dimers, generating rings with graph-set motif R (2) (2)(8). The dimers are further connected into ribbons parallel to the a axis by inter­molecular C—H⋯O hydrogen bonds.