4-(2,4-Dichloro­phen­yl)-5,5-dimethyl-2-(3-silatranyl­propyl­mino)-1,3,2-dioxa­phospho­rinane 2-oxide

In the title compound, C(20)H(31)Cl(2)N(2)O(6)PSi, the dioxaphospho­rinane ring adopts a cis conformation. The silatrane fragment forms a cage-like structure in which there exists an intra­molecular Si—N donor–acceptor bond. In the crystal, centrosymmetrically related mol­ecules are linked by pairs...

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Detalles Bibliográficos
Autores principales: Liu, Zhe-Rong, Tan, Xiao-Jing, Wang, De-Jian, Wang, Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238936/
https://www.ncbi.nlm.nih.gov/pubmed/22199785
http://dx.doi.org/10.1107/S1600536811044928
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author Liu, Zhe-Rong
Tan, Xiao-Jing
Wang, De-Jian
Wang, Yan
author_facet Liu, Zhe-Rong
Tan, Xiao-Jing
Wang, De-Jian
Wang, Yan
author_sort Liu, Zhe-Rong
collection PubMed
description In the title compound, C(20)H(31)Cl(2)N(2)O(6)PSi, the dioxaphospho­rinane ring adopts a cis conformation. The silatrane fragment forms a cage-like structure in which there exists an intra­molecular Si—N donor–acceptor bond. In the crystal, centrosymmetrically related mol­ecules are linked by pairs of N—H⋯O hydrogen bonds into inversion dimers, generating rings with graph-set motif R (2) (2)(8). The dimers are further connected into ribbons parallel to the a axis by inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-32389362011-12-23 4-(2,4-Dichloro­phen­yl)-5,5-dimethyl-2-(3-silatranyl­propyl­mino)-1,3,2-dioxa­phospho­rinane 2-oxide Liu, Zhe-Rong Tan, Xiao-Jing Wang, De-Jian Wang, Yan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(31)Cl(2)N(2)O(6)PSi, the dioxaphospho­rinane ring adopts a cis conformation. The silatrane fragment forms a cage-like structure in which there exists an intra­molecular Si—N donor–acceptor bond. In the crystal, centrosymmetrically related mol­ecules are linked by pairs of N—H⋯O hydrogen bonds into inversion dimers, generating rings with graph-set motif R (2) (2)(8). The dimers are further connected into ribbons parallel to the a axis by inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238936/ /pubmed/22199785 http://dx.doi.org/10.1107/S1600536811044928 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Zhe-Rong
Tan, Xiao-Jing
Wang, De-Jian
Wang, Yan
4-(2,4-Dichloro­phen­yl)-5,5-dimethyl-2-(3-silatranyl­propyl­mino)-1,3,2-dioxa­phospho­rinane 2-oxide
title 4-(2,4-Dichloro­phen­yl)-5,5-dimethyl-2-(3-silatranyl­propyl­mino)-1,3,2-dioxa­phospho­rinane 2-oxide
title_full 4-(2,4-Dichloro­phen­yl)-5,5-dimethyl-2-(3-silatranyl­propyl­mino)-1,3,2-dioxa­phospho­rinane 2-oxide
title_fullStr 4-(2,4-Dichloro­phen­yl)-5,5-dimethyl-2-(3-silatranyl­propyl­mino)-1,3,2-dioxa­phospho­rinane 2-oxide
title_full_unstemmed 4-(2,4-Dichloro­phen­yl)-5,5-dimethyl-2-(3-silatranyl­propyl­mino)-1,3,2-dioxa­phospho­rinane 2-oxide
title_short 4-(2,4-Dichloro­phen­yl)-5,5-dimethyl-2-(3-silatranyl­propyl­mino)-1,3,2-dioxa­phospho­rinane 2-oxide
title_sort 4-(2,4-dichloro­phen­yl)-5,5-dimethyl-2-(3-silatranyl­propyl­mino)-1,3,2-dioxa­phospho­rinane 2-oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238936/
https://www.ncbi.nlm.nih.gov/pubmed/22199785
http://dx.doi.org/10.1107/S1600536811044928
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