N,N′-Diallyl-2,2′,5,5′-tetra­chloro-N,N′-[1,3-phenyl­enebis(methyl­ene)]dibenzene­sulfonamide

In the title compound, C(26)H(24)Cl(4)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 70.07 (12) and 59.07 (12)°. The equivalent angle between the pendant rings is 79.24 (12)°. Both sulfonamide groups lie to the same side of the central ring but the penda...

Descripción completa

Detalles Bibliográficos
Autores principales: Sheikh, Tahir Ali, Ejaz, Khan, Islam Ullah, Harrison, William T. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238937/
https://www.ncbi.nlm.nih.gov/pubmed/22199786
http://dx.doi.org/10.1107/S1600536811045478
Descripción
Sumario:In the title compound, C(26)H(24)Cl(4)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 70.07 (12) and 59.07 (12)°. The equivalent angle between the pendant rings is 79.24 (12)°. Both sulfonamide groups lie to the same side of the central ring but the pendant chains have very different conformations, as indicated by their C—S—N—C torsion angles [104.66 (17) and −76.35 (19)°] and S—N—C—C torsion angles [129.61 (17) and 147.10 (17)°]. Both N atoms are close to planar (bond angle sums = 359.0 and 354.8°). In the crystal, inversion dimers are formed via a pair of weak C—H⋯O inter­actions which generate R (2) (2)(22) loops.

Ejemplares similares