N′-(2-Hy­droxy­benzyl­idene)-2-(hy­droxy­imino)­propano­hydrazide

The mol­ecule of the title compound, C(10)H(11)N(3)O(3), adopts an all-trans conformation and is approxomately planar, the largest deviation from the least-squares plane through all non-H atoms being 0.261 (1) Å. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, the mol­ecules are packe...

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Autores principales: Plutenko, Maxym O., Lampeka, Rostyslav D., Moroz, Yurii S., Haukka, Matti, Pavlova, Svetlana V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238939/
https://www.ncbi.nlm.nih.gov/pubmed/22199788
http://dx.doi.org/10.1107/S1600536811045818
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author Plutenko, Maxym O.
Lampeka, Rostyslav D.
Moroz, Yurii S.
Haukka, Matti
Pavlova, Svetlana V.
author_facet Plutenko, Maxym O.
Lampeka, Rostyslav D.
Moroz, Yurii S.
Haukka, Matti
Pavlova, Svetlana V.
author_sort Plutenko, Maxym O.
collection PubMed
description The mol­ecule of the title compound, C(10)H(11)N(3)O(3), adopts an all-trans conformation and is approxomately planar, the largest deviation from the least-squares plane through all non-H atoms being 0.261 (1) Å. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, the mol­ecules are packed into layers lying parallel to the ab plane by π-stacking inter­actions between the benzene ring of one molecule and the C—N bond of the oxime group of another molecule; the shortest inter­molecular C⋯C separation within the layer is 3.412 (1) Å. The layers are connected by O—H⋯O and N—H⋯O hydrogen bonds.
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spelling pubmed-32389392011-12-23 N′-(2-Hy­droxy­benzyl­idene)-2-(hy­droxy­imino)­propano­hydrazide Plutenko, Maxym O. Lampeka, Rostyslav D. Moroz, Yurii S. Haukka, Matti Pavlova, Svetlana V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(10)H(11)N(3)O(3), adopts an all-trans conformation and is approxomately planar, the largest deviation from the least-squares plane through all non-H atoms being 0.261 (1) Å. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, the mol­ecules are packed into layers lying parallel to the ab plane by π-stacking inter­actions between the benzene ring of one molecule and the C—N bond of the oxime group of another molecule; the shortest inter­molecular C⋯C separation within the layer is 3.412 (1) Å. The layers are connected by O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238939/ /pubmed/22199788 http://dx.doi.org/10.1107/S1600536811045818 Text en © Plutenko et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Plutenko, Maxym O.
Lampeka, Rostyslav D.
Moroz, Yurii S.
Haukka, Matti
Pavlova, Svetlana V.
N′-(2-Hy­droxy­benzyl­idene)-2-(hy­droxy­imino)­propano­hydrazide
title N′-(2-Hy­droxy­benzyl­idene)-2-(hy­droxy­imino)­propano­hydrazide
title_full N′-(2-Hy­droxy­benzyl­idene)-2-(hy­droxy­imino)­propano­hydrazide
title_fullStr N′-(2-Hy­droxy­benzyl­idene)-2-(hy­droxy­imino)­propano­hydrazide
title_full_unstemmed N′-(2-Hy­droxy­benzyl­idene)-2-(hy­droxy­imino)­propano­hydrazide
title_short N′-(2-Hy­droxy­benzyl­idene)-2-(hy­droxy­imino)­propano­hydrazide
title_sort n′-(2-hy­droxy­benzyl­idene)-2-(hy­droxy­imino)­propano­hydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238939/
https://www.ncbi.nlm.nih.gov/pubmed/22199788
http://dx.doi.org/10.1107/S1600536811045818
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