N′-(2-Hydroxybenzylidene)-2-(hydroxyimino)propanohydrazide
The molecule of the title compound, C(10)H(11)N(3)O(3), adopts an all-trans conformation and is approxomately planar, the largest deviation from the least-squares plane through all non-H atoms being 0.261 (1) Å. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, the molecules are packe...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238939/ https://www.ncbi.nlm.nih.gov/pubmed/22199788 http://dx.doi.org/10.1107/S1600536811045818 |
_version_ | 1782219088257351680 |
---|---|
author | Plutenko, Maxym O. Lampeka, Rostyslav D. Moroz, Yurii S. Haukka, Matti Pavlova, Svetlana V. |
author_facet | Plutenko, Maxym O. Lampeka, Rostyslav D. Moroz, Yurii S. Haukka, Matti Pavlova, Svetlana V. |
author_sort | Plutenko, Maxym O. |
collection | PubMed |
description | The molecule of the title compound, C(10)H(11)N(3)O(3), adopts an all-trans conformation and is approxomately planar, the largest deviation from the least-squares plane through all non-H atoms being 0.261 (1) Å. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, the molecules are packed into layers lying parallel to the ab plane by π-stacking interactions between the benzene ring of one molecule and the C—N bond of the oxime group of another molecule; the shortest intermolecular C⋯C separation within the layer is 3.412 (1) Å. The layers are connected by O—H⋯O and N—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3238939 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32389392011-12-23 N′-(2-Hydroxybenzylidene)-2-(hydroxyimino)propanohydrazide Plutenko, Maxym O. Lampeka, Rostyslav D. Moroz, Yurii S. Haukka, Matti Pavlova, Svetlana V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(10)H(11)N(3)O(3), adopts an all-trans conformation and is approxomately planar, the largest deviation from the least-squares plane through all non-H atoms being 0.261 (1) Å. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, the molecules are packed into layers lying parallel to the ab plane by π-stacking interactions between the benzene ring of one molecule and the C—N bond of the oxime group of another molecule; the shortest intermolecular C⋯C separation within the layer is 3.412 (1) Å. The layers are connected by O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238939/ /pubmed/22199788 http://dx.doi.org/10.1107/S1600536811045818 Text en © Plutenko et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Plutenko, Maxym O. Lampeka, Rostyslav D. Moroz, Yurii S. Haukka, Matti Pavlova, Svetlana V. N′-(2-Hydroxybenzylidene)-2-(hydroxyimino)propanohydrazide |
title |
N′-(2-Hydroxybenzylidene)-2-(hydroxyimino)propanohydrazide |
title_full |
N′-(2-Hydroxybenzylidene)-2-(hydroxyimino)propanohydrazide |
title_fullStr |
N′-(2-Hydroxybenzylidene)-2-(hydroxyimino)propanohydrazide |
title_full_unstemmed |
N′-(2-Hydroxybenzylidene)-2-(hydroxyimino)propanohydrazide |
title_short |
N′-(2-Hydroxybenzylidene)-2-(hydroxyimino)propanohydrazide |
title_sort | n′-(2-hydroxybenzylidene)-2-(hydroxyimino)propanohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238939/ https://www.ncbi.nlm.nih.gov/pubmed/22199788 http://dx.doi.org/10.1107/S1600536811045818 |
work_keys_str_mv | AT plutenkomaxymo n2hydroxybenzylidene2hydroxyiminopropanohydrazide AT lampekarostyslavd n2hydroxybenzylidene2hydroxyiminopropanohydrazide AT morozyuriis n2hydroxybenzylidene2hydroxyiminopropanohydrazide AT haukkamatti n2hydroxybenzylidene2hydroxyiminopropanohydrazide AT pavlovasvetlanav n2hydroxybenzylidene2hydroxyiminopropanohydrazide |