5-[(1H-Benzimidazol-1-yl)meth­yl]benzene-1,3-dicarb­oxy­lic acid

Crystals of the title compound, C(16)H(12)N(2)O(4), were obtained accidentally from a hydro­thermal reaction of 5-[(1H-benzimidazol-1-yl)meth­yl]isophthalic acid with manganese bromide in the presence of N,N′-dimethyl­formamide. In the title mol­ecule, the benzimidazole ring system is almost planar,...

Descripción completa

Detalles Bibliográficos
Autor principal: Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238952/
https://www.ncbi.nlm.nih.gov/pubmed/22199801
http://dx.doi.org/10.1107/S1600536811047416
_version_ 1782219091143032832
author Cheng, Xiao-Chun
author_facet Cheng, Xiao-Chun
author_sort Cheng, Xiao-Chun
collection PubMed
description Crystals of the title compound, C(16)H(12)N(2)O(4), were obtained accidentally from a hydro­thermal reaction of 5-[(1H-benzimidazol-1-yl)meth­yl]isophthalic acid with manganese bromide in the presence of N,N′-dimethyl­formamide. In the title mol­ecule, the benzimidazole ring system is almost planar, with a maximum deviation from the mean plane of 0.010 (2) Å. The benzimidazole and central benzene rings are inclined at a dihedral angle of 71.7 (6)°. The crystal structure is stabilized by O—H⋯N and O—H⋯O hydrogen bonds.
format Online
Article
Text
id pubmed-3238952
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32389522011-12-23 5-[(1H-Benzimidazol-1-yl)meth­yl]benzene-1,3-dicarb­oxy­lic acid Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(16)H(12)N(2)O(4), were obtained accidentally from a hydro­thermal reaction of 5-[(1H-benzimidazol-1-yl)meth­yl]isophthalic acid with manganese bromide in the presence of N,N′-dimethyl­formamide. In the title mol­ecule, the benzimidazole ring system is almost planar, with a maximum deviation from the mean plane of 0.010 (2) Å. The benzimidazole and central benzene rings are inclined at a dihedral angle of 71.7 (6)°. The crystal structure is stabilized by O—H⋯N and O—H⋯O hydrogen bonds. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238952/ /pubmed/22199801 http://dx.doi.org/10.1107/S1600536811047416 Text en © Xiao-Chun Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cheng, Xiao-Chun
5-[(1H-Benzimidazol-1-yl)meth­yl]benzene-1,3-dicarb­oxy­lic acid
title 5-[(1H-Benzimidazol-1-yl)meth­yl]benzene-1,3-dicarb­oxy­lic acid
title_full 5-[(1H-Benzimidazol-1-yl)meth­yl]benzene-1,3-dicarb­oxy­lic acid
title_fullStr 5-[(1H-Benzimidazol-1-yl)meth­yl]benzene-1,3-dicarb­oxy­lic acid
title_full_unstemmed 5-[(1H-Benzimidazol-1-yl)meth­yl]benzene-1,3-dicarb­oxy­lic acid
title_short 5-[(1H-Benzimidazol-1-yl)meth­yl]benzene-1,3-dicarb­oxy­lic acid
title_sort 5-[(1h-benzimidazol-1-yl)meth­yl]benzene-1,3-dicarb­oxy­lic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238952/
https://www.ncbi.nlm.nih.gov/pubmed/22199801
http://dx.doi.org/10.1107/S1600536811047416
work_keys_str_mv AT chengxiaochun 51hbenzimidazol1ylmethylbenzene13dicarboxylicacid

Ejemplares similares