N,N′-Bis(pyridin-2-yl)benzene-1,4-diamine–naphthalene (2/1)

The asymmetric unit of the title compound, C(10)H(8)·2C(16)H(14)N(4), consists of one mol­ecule of N,N′-bis­(pyridin-2-yl)benzene-1,4-diamine (PDAB) and one half of the centrosymmetric naphthalene mol­ecule. The PDAB mol­ecule adopts a non-planar conformation with an E configuration at the two parti...

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Detalles Bibliográficos
Autores principales: Wicher, Barbara, Gdaniec, Maria
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238953/
https://www.ncbi.nlm.nih.gov/pubmed/22199802
http://dx.doi.org/10.1107/S1600536811047519
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author Wicher, Barbara
Gdaniec, Maria
author_facet Wicher, Barbara
Gdaniec, Maria
author_sort Wicher, Barbara
collection PubMed
description The asymmetric unit of the title compound, C(10)H(8)·2C(16)H(14)N(4), consists of one mol­ecule of N,N′-bis­(pyridin-2-yl)benzene-1,4-diamine (PDAB) and one half of the centrosymmetric naphthalene mol­ecule. The PDAB mol­ecule adopts a non-planar conformation with an E configuration at the two partially double exo C N bonds of the 2-pyridyl­amine units. In the crystal, N—H⋯N hydrogen bonds between the PDAB mol­ecules generate a cyclic R (2) (2)(8) motif, leading to the formation of PDAB tapes extending along [100]. The tapes are arranged into (010) layers and the naphthalene mol­ecules are enclosed in cavities formed between the PDAB layers.
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spelling pubmed-32389532011-12-23 N,N′-Bis(pyridin-2-yl)benzene-1,4-diamine–naphthalene (2/1) Wicher, Barbara Gdaniec, Maria Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(8)·2C(16)H(14)N(4), consists of one mol­ecule of N,N′-bis­(pyridin-2-yl)benzene-1,4-diamine (PDAB) and one half of the centrosymmetric naphthalene mol­ecule. The PDAB mol­ecule adopts a non-planar conformation with an E configuration at the two partially double exo C N bonds of the 2-pyridyl­amine units. In the crystal, N—H⋯N hydrogen bonds between the PDAB mol­ecules generate a cyclic R (2) (2)(8) motif, leading to the formation of PDAB tapes extending along [100]. The tapes are arranged into (010) layers and the naphthalene mol­ecules are enclosed in cavities formed between the PDAB layers. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238953/ /pubmed/22199802 http://dx.doi.org/10.1107/S1600536811047519 Text en © Wicher and Gdaniec 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wicher, Barbara
Gdaniec, Maria
N,N′-Bis(pyridin-2-yl)benzene-1,4-diamine–naphthalene (2/1)
title N,N′-Bis(pyridin-2-yl)benzene-1,4-diamine–naphthalene (2/1)
title_full N,N′-Bis(pyridin-2-yl)benzene-1,4-diamine–naphthalene (2/1)
title_fullStr N,N′-Bis(pyridin-2-yl)benzene-1,4-diamine–naphthalene (2/1)
title_full_unstemmed N,N′-Bis(pyridin-2-yl)benzene-1,4-diamine–naphthalene (2/1)
title_short N,N′-Bis(pyridin-2-yl)benzene-1,4-diamine–naphthalene (2/1)
title_sort n,n′-bis(pyridin-2-yl)benzene-1,4-diamine–naphthalene (2/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238953/
https://www.ncbi.nlm.nih.gov/pubmed/22199802
http://dx.doi.org/10.1107/S1600536811047519
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