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9-(4-Bromophenyl)-3,6-di-tert-butyl-9H-carbazole
The asymmetric unit of the title compound, C(26)H(28)BrN, contains two independent molecules in which the carbazole rings are almost planar, with r.m.s. deviations of 0.0212 (1) and 0.0229 (1) Å. The dihedral angles between the carbazole ring system and the pendent benzene ring are 60.5 (1) and 56....
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238959/ https://www.ncbi.nlm.nih.gov/pubmed/22199808 http://dx.doi.org/10.1107/S1600536811047386 |
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author | Zhang, Jing-Ya Zhang, Wei-Yi |
author_facet | Zhang, Jing-Ya Zhang, Wei-Yi |
author_sort | Zhang, Jing-Ya |
collection | PubMed |
description | The asymmetric unit of the title compound, C(26)H(28)BrN, contains two independent molecules in which the carbazole rings are almost planar, with r.m.s. deviations of 0.0212 (1) and 0.0229 (1) Å. The dihedral angles between the carbazole ring system and the pendent benzene ring are 60.5 (1) and 56.3 (1)° in the two molecules. In the crystal, molecules are linked into chains along the b axis by C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3238959 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32389592011-12-23 9-(4-Bromophenyl)-3,6-di-tert-butyl-9H-carbazole Zhang, Jing-Ya Zhang, Wei-Yi Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(26)H(28)BrN, contains two independent molecules in which the carbazole rings are almost planar, with r.m.s. deviations of 0.0212 (1) and 0.0229 (1) Å. The dihedral angles between the carbazole ring system and the pendent benzene ring are 60.5 (1) and 56.3 (1)° in the two molecules. In the crystal, molecules are linked into chains along the b axis by C—H⋯π interactions. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238959/ /pubmed/22199808 http://dx.doi.org/10.1107/S1600536811047386 Text en © Zhang and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Jing-Ya Zhang, Wei-Yi 9-(4-Bromophenyl)-3,6-di-tert-butyl-9H-carbazole |
title | 9-(4-Bromophenyl)-3,6-di-tert-butyl-9H-carbazole |
title_full | 9-(4-Bromophenyl)-3,6-di-tert-butyl-9H-carbazole |
title_fullStr | 9-(4-Bromophenyl)-3,6-di-tert-butyl-9H-carbazole |
title_full_unstemmed | 9-(4-Bromophenyl)-3,6-di-tert-butyl-9H-carbazole |
title_short | 9-(4-Bromophenyl)-3,6-di-tert-butyl-9H-carbazole |
title_sort | 9-(4-bromophenyl)-3,6-di-tert-butyl-9h-carbazole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238959/ https://www.ncbi.nlm.nih.gov/pubmed/22199808 http://dx.doi.org/10.1107/S1600536811047386 |
work_keys_str_mv | AT zhangjingya 94bromophenyl36ditertbutyl9hcarbazole AT zhangweiyi 94bromophenyl36ditertbutyl9hcarbazole |