1,1′-Binaphthyl-2,2′-diyl benzyl­phos­phoramidate

In the title compound, C(27)H(20)NO(3)P, the P atom exhibits a somewhat distorted PNO(3) tetra­hedral geometry, with the O—P—O angle for the binaphthyl fragment being 102.82 (6)°. The dihedral angle between the naphthyl ring systems is 59.00 (2)°. In the crystal, inversion dimers linked by pairs of...

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Autores principales: Gowda, Ravikumar R, Ramkumar, Venkatachalam, Chakraborty, Debashis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238962/
https://www.ncbi.nlm.nih.gov/pubmed/22199811
http://dx.doi.org/10.1107/S1600536811046861
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author Gowda, Ravikumar R
Ramkumar, Venkatachalam
Chakraborty, Debashis
author_facet Gowda, Ravikumar R
Ramkumar, Venkatachalam
Chakraborty, Debashis
author_sort Gowda, Ravikumar R
collection PubMed
description In the title compound, C(27)H(20)NO(3)P, the P atom exhibits a somewhat distorted PNO(3) tetra­hedral geometry, with the O—P—O angle for the binaphthyl fragment being 102.82 (6)°. The dihedral angle between the naphthyl ring systems is 59.00 (2)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops.
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spelling pubmed-32389622011-12-23 1,1′-Binaphthyl-2,2′-diyl benzyl­phos­phoramidate Gowda, Ravikumar R Ramkumar, Venkatachalam Chakraborty, Debashis Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(20)NO(3)P, the P atom exhibits a somewhat distorted PNO(3) tetra­hedral geometry, with the O—P—O angle for the binaphthyl fragment being 102.82 (6)°. The dihedral angle between the naphthyl ring systems is 59.00 (2)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238962/ /pubmed/22199811 http://dx.doi.org/10.1107/S1600536811046861 Text en © Gowda et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, Ravikumar R
Ramkumar, Venkatachalam
Chakraborty, Debashis
1,1′-Binaphthyl-2,2′-diyl benzyl­phos­phoramidate
title 1,1′-Binaphthyl-2,2′-diyl benzyl­phos­phoramidate
title_full 1,1′-Binaphthyl-2,2′-diyl benzyl­phos­phoramidate
title_fullStr 1,1′-Binaphthyl-2,2′-diyl benzyl­phos­phoramidate
title_full_unstemmed 1,1′-Binaphthyl-2,2′-diyl benzyl­phos­phoramidate
title_short 1,1′-Binaphthyl-2,2′-diyl benzyl­phos­phoramidate
title_sort 1,1′-binaphthyl-2,2′-diyl benzyl­phos­phoramidate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238962/
https://www.ncbi.nlm.nih.gov/pubmed/22199811
http://dx.doi.org/10.1107/S1600536811046861
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