1-[((E)-{2-[(2-Nitro­benz­yl)(2-{[(E)-(2-oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}eth­yl)amino]­eth­yl}aza­niumyl­idene)meth­yl]naphthalen-2-olate monohydrate

The title Schiff base compound, C(33)H(30)N(4)O(4)·H(2)O, adopts an E configuration with respect to each C=N double bond. In the mol­ecule, there are naphthoxide anions and the protonated imino N atoms. Intra­molecular N—H⋯O hydrogen bonds lead to the formation of approximately planar (maximum devia...

Descripción completa

Detalles Bibliográficos
Autores principales: Menati, Saeid, Amiri Rudbari, Hadi, Azadbakht, Reza, Bruno, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238971/
https://www.ncbi.nlm.nih.gov/pubmed/22199820
http://dx.doi.org/10.1107/S1600536811047465
Descripción
Sumario:The title Schiff base compound, C(33)H(30)N(4)O(4)·H(2)O, adopts an E configuration with respect to each C=N double bond. In the mol­ecule, there are naphthoxide anions and the protonated imino N atoms. Intra­molecular N—H⋯O hydrogen bonds lead to the formation of approximately planar (maximum deviation 0.029 Å for H atom) six-membered rings.. In the crystal, mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds as well as C—H⋯O contacts, leading to the formation of a three-dimensional network.

Ejemplares similares