1-[((E)-{2-[(2-Nitro­benz­yl)(2-{[(E)-(2-oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}eth­yl)amino]­eth­yl}aza­niumyl­idene)meth­yl]naphthalen-2-olate monohydrate

The title Schiff base compound, C(33)H(30)N(4)O(4)·H(2)O, adopts an E configuration with respect to each C=N double bond. In the mol­ecule, there are naphthoxide anions and the protonated imino N atoms. Intra­molecular N—H⋯O hydrogen bonds lead to the formation of approximately planar (maximum devia...

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Autores principales: Menati, Saeid, Amiri Rudbari, Hadi, Azadbakht, Reza, Bruno, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238971/
https://www.ncbi.nlm.nih.gov/pubmed/22199820
http://dx.doi.org/10.1107/S1600536811047465
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author Menati, Saeid
Amiri Rudbari, Hadi
Azadbakht, Reza
Bruno, Giuseppe
author_facet Menati, Saeid
Amiri Rudbari, Hadi
Azadbakht, Reza
Bruno, Giuseppe
author_sort Menati, Saeid
collection PubMed
description The title Schiff base compound, C(33)H(30)N(4)O(4)·H(2)O, adopts an E configuration with respect to each C=N double bond. In the mol­ecule, there are naphthoxide anions and the protonated imino N atoms. Intra­molecular N—H⋯O hydrogen bonds lead to the formation of approximately planar (maximum deviation 0.029 Å for H atom) six-membered rings.. In the crystal, mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds as well as C—H⋯O contacts, leading to the formation of a three-dimensional network.
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spelling pubmed-32389712011-12-23 1-[((E)-{2-[(2-Nitro­benz­yl)(2-{[(E)-(2-oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}eth­yl)amino]­eth­yl}aza­niumyl­idene)meth­yl]naphthalen-2-olate monohydrate Menati, Saeid Amiri Rudbari, Hadi Azadbakht, Reza Bruno, Giuseppe Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(33)H(30)N(4)O(4)·H(2)O, adopts an E configuration with respect to each C=N double bond. In the mol­ecule, there are naphthoxide anions and the protonated imino N atoms. Intra­molecular N—H⋯O hydrogen bonds lead to the formation of approximately planar (maximum deviation 0.029 Å for H atom) six-membered rings.. In the crystal, mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds as well as C—H⋯O contacts, leading to the formation of a three-dimensional network. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238971/ /pubmed/22199820 http://dx.doi.org/10.1107/S1600536811047465 Text en © Menati et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Menati, Saeid
Amiri Rudbari, Hadi
Azadbakht, Reza
Bruno, Giuseppe
1-[((E)-{2-[(2-Nitro­benz­yl)(2-{[(E)-(2-oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}eth­yl)amino]­eth­yl}aza­niumyl­idene)meth­yl]naphthalen-2-olate monohydrate
title 1-[((E)-{2-[(2-Nitro­benz­yl)(2-{[(E)-(2-oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}eth­yl)amino]­eth­yl}aza­niumyl­idene)meth­yl]naphthalen-2-olate monohydrate
title_full 1-[((E)-{2-[(2-Nitro­benz­yl)(2-{[(E)-(2-oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}eth­yl)amino]­eth­yl}aza­niumyl­idene)meth­yl]naphthalen-2-olate monohydrate
title_fullStr 1-[((E)-{2-[(2-Nitro­benz­yl)(2-{[(E)-(2-oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}eth­yl)amino]­eth­yl}aza­niumyl­idene)meth­yl]naphthalen-2-olate monohydrate
title_full_unstemmed 1-[((E)-{2-[(2-Nitro­benz­yl)(2-{[(E)-(2-oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}eth­yl)amino]­eth­yl}aza­niumyl­idene)meth­yl]naphthalen-2-olate monohydrate
title_short 1-[((E)-{2-[(2-Nitro­benz­yl)(2-{[(E)-(2-oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}eth­yl)amino]­eth­yl}aza­niumyl­idene)meth­yl]naphthalen-2-olate monohydrate
title_sort 1-[((e)-{2-[(2-nitro­benz­yl)(2-{[(e)-(2-oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}eth­yl)amino]­eth­yl}aza­niumyl­idene)meth­yl]naphthalen-2-olate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238971/
https://www.ncbi.nlm.nih.gov/pubmed/22199820
http://dx.doi.org/10.1107/S1600536811047465
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AT azadbakhtreza 1e22nitrobenzyl2e2oxidonaphthalen1ylmethylideneazaniumylethylaminoethylazaniumylidenemethylnaphthalen2olatemonohydrate
AT brunogiuseppe 1e22nitrobenzyl2e2oxidonaphthalen1ylmethylideneazaniumylethylaminoethylazaniumylidenemethylnaphthalen2olatemonohydrate

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