Cargando…

1,3-Bis(propan-2-yl)naphthalene

In the title compound, C(16)H(20), one of the isopropyl groups shows almost equal displacements [1.252 (1) and −1.270 (1) Å] of its methyl-C atoms from the mean plane of the naphthalene ring system, while the other shows asymmetric displacements [1.586 (2) and −0.315 (1) Å]. In the crystal, the mol­...

Descripción completa

Detalles Bibliográficos
Autores principales: Schröder, Bernd, Gomes, Ligia Rebelo, Low, John Nicolson
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238981/
https://www.ncbi.nlm.nih.gov/pubmed/22199830
http://dx.doi.org/10.1107/S1600536811047854
_version_ 1782219097609601024
author Schröder, Bernd
Gomes, Ligia Rebelo
Low, John Nicolson
author_facet Schröder, Bernd
Gomes, Ligia Rebelo
Low, John Nicolson
author_sort Schröder, Bernd
collection PubMed
description In the title compound, C(16)H(20), one of the isopropyl groups shows almost equal displacements [1.252 (1) and −1.270 (1) Å] of its methyl-C atoms from the mean plane of the naphthalene ring system, while the other shows asymmetric displacements [1.586 (2) and −0.315 (1) Å]. In the crystal, the mol­ecules are linked into sheets lying in the ab plane by three C—H⋯π contacts, two involving donors belonging to the isopropyl groups and the third a donor atom from the naphthalene ring system. The different orientations of the isopropyl groups might be attributed to the fact that the C—H⋯π inter­action involving one of them is enhanced by the C—H⋯π inter­action involving the aromatic ring.
format Online
Article
Text
id pubmed-3238981
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32389812011-12-23 1,3-Bis(propan-2-yl)naphthalene Schröder, Bernd Gomes, Ligia Rebelo Low, John Nicolson Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(20), one of the isopropyl groups shows almost equal displacements [1.252 (1) and −1.270 (1) Å] of its methyl-C atoms from the mean plane of the naphthalene ring system, while the other shows asymmetric displacements [1.586 (2) and −0.315 (1) Å]. In the crystal, the mol­ecules are linked into sheets lying in the ab plane by three C—H⋯π contacts, two involving donors belonging to the isopropyl groups and the third a donor atom from the naphthalene ring system. The different orientations of the isopropyl groups might be attributed to the fact that the C—H⋯π inter­action involving one of them is enhanced by the C—H⋯π inter­action involving the aromatic ring. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238981/ /pubmed/22199830 http://dx.doi.org/10.1107/S1600536811047854 Text en © Schröder et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Schröder, Bernd
Gomes, Ligia Rebelo
Low, John Nicolson
1,3-Bis(propan-2-yl)naphthalene
title 1,3-Bis(propan-2-yl)naphthalene
title_full 1,3-Bis(propan-2-yl)naphthalene
title_fullStr 1,3-Bis(propan-2-yl)naphthalene
title_full_unstemmed 1,3-Bis(propan-2-yl)naphthalene
title_short 1,3-Bis(propan-2-yl)naphthalene
title_sort 1,3-bis(propan-2-yl)naphthalene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238981/
https://www.ncbi.nlm.nih.gov/pubmed/22199830
http://dx.doi.org/10.1107/S1600536811047854
work_keys_str_mv AT schroderbernd 13bispropan2ylnaphthalene
AT gomesligiarebelo 13bispropan2ylnaphthalene
AT lowjohnnicolson 13bispropan2ylnaphthalene