Cargando…
1,3-Bis(propan-2-yl)naphthalene
In the title compound, C(16)H(20), one of the isopropyl groups shows almost equal displacements [1.252 (1) and −1.270 (1) Å] of its methyl-C atoms from the mean plane of the naphthalene ring system, while the other shows asymmetric displacements [1.586 (2) and −0.315 (1) Å]. In the crystal, the mol...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238981/ https://www.ncbi.nlm.nih.gov/pubmed/22199830 http://dx.doi.org/10.1107/S1600536811047854 |
_version_ | 1782219097609601024 |
---|---|
author | Schröder, Bernd Gomes, Ligia Rebelo Low, John Nicolson |
author_facet | Schröder, Bernd Gomes, Ligia Rebelo Low, John Nicolson |
author_sort | Schröder, Bernd |
collection | PubMed |
description | In the title compound, C(16)H(20), one of the isopropyl groups shows almost equal displacements [1.252 (1) and −1.270 (1) Å] of its methyl-C atoms from the mean plane of the naphthalene ring system, while the other shows asymmetric displacements [1.586 (2) and −0.315 (1) Å]. In the crystal, the molecules are linked into sheets lying in the ab plane by three C—H⋯π contacts, two involving donors belonging to the isopropyl groups and the third a donor atom from the naphthalene ring system. The different orientations of the isopropyl groups might be attributed to the fact that the C—H⋯π interaction involving one of them is enhanced by the C—H⋯π interaction involving the aromatic ring. |
format | Online Article Text |
id | pubmed-3238981 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32389812011-12-23 1,3-Bis(propan-2-yl)naphthalene Schröder, Bernd Gomes, Ligia Rebelo Low, John Nicolson Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(20), one of the isopropyl groups shows almost equal displacements [1.252 (1) and −1.270 (1) Å] of its methyl-C atoms from the mean plane of the naphthalene ring system, while the other shows asymmetric displacements [1.586 (2) and −0.315 (1) Å]. In the crystal, the molecules are linked into sheets lying in the ab plane by three C—H⋯π contacts, two involving donors belonging to the isopropyl groups and the third a donor atom from the naphthalene ring system. The different orientations of the isopropyl groups might be attributed to the fact that the C—H⋯π interaction involving one of them is enhanced by the C—H⋯π interaction involving the aromatic ring. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238981/ /pubmed/22199830 http://dx.doi.org/10.1107/S1600536811047854 Text en © Schröder et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Schröder, Bernd Gomes, Ligia Rebelo Low, John Nicolson 1,3-Bis(propan-2-yl)naphthalene |
title | 1,3-Bis(propan-2-yl)naphthalene |
title_full | 1,3-Bis(propan-2-yl)naphthalene |
title_fullStr | 1,3-Bis(propan-2-yl)naphthalene |
title_full_unstemmed | 1,3-Bis(propan-2-yl)naphthalene |
title_short | 1,3-Bis(propan-2-yl)naphthalene |
title_sort | 1,3-bis(propan-2-yl)naphthalene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238981/ https://www.ncbi.nlm.nih.gov/pubmed/22199830 http://dx.doi.org/10.1107/S1600536811047854 |
work_keys_str_mv | AT schroderbernd 13bispropan2ylnaphthalene AT gomesligiarebelo 13bispropan2ylnaphthalene AT lowjohnnicolson 13bispropan2ylnaphthalene |