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5-Chloro-1-nonyl-1H-benzimidazol-2(3H)-one

The asymmetric unit of the title compound, C(16)H(23)ClN(2)O, comtains two independent mol­ecules in which the fused-ring systems are essentially planar, the largest deviation from the mean plane of each mol­ecule being 0.011 (2) Å and 0.016 (2) Å. The benzimidazole rings of the two mol­ecules make...

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Autores principales: Kandri Rodi, Youssef, Ouazzani Chahdi, Fouad, Essassi, El Mokhtar, Luis, Santiago V., Bolte, Michael, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238987/
https://www.ncbi.nlm.nih.gov/pubmed/22199836
http://dx.doi.org/10.1107/S1600536811047829
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author Kandri Rodi, Youssef
Ouazzani Chahdi, Fouad
Essassi, El Mokhtar
Luis, Santiago V.
Bolte, Michael
El Ammari, Lahcen
author_facet Kandri Rodi, Youssef
Ouazzani Chahdi, Fouad
Essassi, El Mokhtar
Luis, Santiago V.
Bolte, Michael
El Ammari, Lahcen
author_sort Kandri Rodi, Youssef
collection PubMed
description The asymmetric unit of the title compound, C(16)H(23)ClN(2)O, comtains two independent mol­ecules in which the fused-ring systems are essentially planar, the largest deviation from the mean plane of each mol­ecule being 0.011 (2) Å and 0.016 (2) Å. The benzimidazole rings of the two mol­ecules make a dihedral angle of 66.65 (7)°. The nonyl substituents are almost perpendicular to the benzimidazole planes [C—N—C—C tosrsion angles = 96.0 (3) and 81.0 (2)°]. In the crystal, each independent molecule forms an inversion dimer via a pair of N—H⋯O hydrogen bonds. In one of the independent molecules, the terminal –CH(2)–CH(3) group of the alkyl chain is disordered over two sets of sites with a refined occupancy ratio of 0.746 (7):0.254 (7).
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spelling pubmed-32389872011-12-23 5-Chloro-1-nonyl-1H-benzimidazol-2(3H)-one Kandri Rodi, Youssef Ouazzani Chahdi, Fouad Essassi, El Mokhtar Luis, Santiago V. Bolte, Michael El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(16)H(23)ClN(2)O, comtains two independent mol­ecules in which the fused-ring systems are essentially planar, the largest deviation from the mean plane of each mol­ecule being 0.011 (2) Å and 0.016 (2) Å. The benzimidazole rings of the two mol­ecules make a dihedral angle of 66.65 (7)°. The nonyl substituents are almost perpendicular to the benzimidazole planes [C—N—C—C tosrsion angles = 96.0 (3) and 81.0 (2)°]. In the crystal, each independent molecule forms an inversion dimer via a pair of N—H⋯O hydrogen bonds. In one of the independent molecules, the terminal –CH(2)–CH(3) group of the alkyl chain is disordered over two sets of sites with a refined occupancy ratio of 0.746 (7):0.254 (7). International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238987/ /pubmed/22199836 http://dx.doi.org/10.1107/S1600536811047829 Text en © Kandri Rodi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kandri Rodi, Youssef
Ouazzani Chahdi, Fouad
Essassi, El Mokhtar
Luis, Santiago V.
Bolte, Michael
El Ammari, Lahcen
5-Chloro-1-nonyl-1H-benzimidazol-2(3H)-one
title 5-Chloro-1-nonyl-1H-benzimidazol-2(3H)-one
title_full 5-Chloro-1-nonyl-1H-benzimidazol-2(3H)-one
title_fullStr 5-Chloro-1-nonyl-1H-benzimidazol-2(3H)-one
title_full_unstemmed 5-Chloro-1-nonyl-1H-benzimidazol-2(3H)-one
title_short 5-Chloro-1-nonyl-1H-benzimidazol-2(3H)-one
title_sort 5-chloro-1-nonyl-1h-benzimidazol-2(3h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238987/
https://www.ncbi.nlm.nih.gov/pubmed/22199836
http://dx.doi.org/10.1107/S1600536811047829
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