Cargando…
4-[(4-Chlorophenyl)(hydroxy)methylidene]isochromane-1,3-dione
In the title compound, C(16)H(9)ClO(4), the six-membered heterocyclic ring adopts a screw-boat conformation. The benzene rings are oriented to each other at a dihedral angle of 59.26 (9)°. The molecular structure exhibits a ring motif, viz. S(6), owing to an intramolecular O—H⋯O hydrogen bond. The...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238994/ https://www.ncbi.nlm.nih.gov/pubmed/22199843 http://dx.doi.org/10.1107/S160053681104829X |
Sumario: | In the title compound, C(16)H(9)ClO(4), the six-membered heterocyclic ring adopts a screw-boat conformation. The benzene rings are oriented to each other at a dihedral angle of 59.26 (9)°. The molecular structure exhibits a ring motif, viz. S(6), owing to an intramolecular O—H⋯O hydrogen bond. The presence of C—H⋯O contacts generates an infinite chain along [001]. Also present are π–π stacking interactions between neighbouring isochromanedione benzene rings [centroid–centroid distance = 3.746 (1) Å], and C—O⋯π interactions [O⋯centroid = 3.934 (2) Å]. |
---|