Ethyl 2-[N-(tert-butyl­sulfin­yl)carbamo­yl]benzoate

The title compound, C(14)H(19)NO(4)S, was obtained in quanti­tative yield by Lewis acid-catalysed alcoholysis of a phtalimide precursor. An intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, centrosymmetric dimers are formed by pairs of N—H⋯O hydrogen bonds between the sulfinyl O atoms and...

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Detalles Bibliográficos
Autores principales: Honraedt, Aurelien, Ladeira, Sonia, Berranger, Thierry, Gras, Emmanuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238995/
https://www.ncbi.nlm.nih.gov/pubmed/22199844
http://dx.doi.org/10.1107/S1600536811047027
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author Honraedt, Aurelien
Ladeira, Sonia
Berranger, Thierry
Gras, Emmanuel
author_facet Honraedt, Aurelien
Ladeira, Sonia
Berranger, Thierry
Gras, Emmanuel
author_sort Honraedt, Aurelien
collection PubMed
description The title compound, C(14)H(19)NO(4)S, was obtained in quanti­tative yield by Lewis acid-catalysed alcoholysis of a phtalimide precursor. An intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, centrosymmetric dimers are formed by pairs of N—H⋯O hydrogen bonds between the sulfinyl O atoms and the carbamoyl N—H group of a neighboring mol­ecule. C—H⋯O inter­actions feature in the crystal structure.
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spelling pubmed-32389952011-12-23 Ethyl 2-[N-(tert-butyl­sulfin­yl)carbamo­yl]benzoate Honraedt, Aurelien Ladeira, Sonia Berranger, Thierry Gras, Emmanuel Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(19)NO(4)S, was obtained in quanti­tative yield by Lewis acid-catalysed alcoholysis of a phtalimide precursor. An intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, centrosymmetric dimers are formed by pairs of N—H⋯O hydrogen bonds between the sulfinyl O atoms and the carbamoyl N—H group of a neighboring mol­ecule. C—H⋯O inter­actions feature in the crystal structure. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3238995/ /pubmed/22199844 http://dx.doi.org/10.1107/S1600536811047027 Text en © Honraedt et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Honraedt, Aurelien
Ladeira, Sonia
Berranger, Thierry
Gras, Emmanuel
Ethyl 2-[N-(tert-butyl­sulfin­yl)carbamo­yl]benzoate
title Ethyl 2-[N-(tert-butyl­sulfin­yl)carbamo­yl]benzoate
title_full Ethyl 2-[N-(tert-butyl­sulfin­yl)carbamo­yl]benzoate
title_fullStr Ethyl 2-[N-(tert-butyl­sulfin­yl)carbamo­yl]benzoate
title_full_unstemmed Ethyl 2-[N-(tert-butyl­sulfin­yl)carbamo­yl]benzoate
title_short Ethyl 2-[N-(tert-butyl­sulfin­yl)carbamo­yl]benzoate
title_sort ethyl 2-[n-(tert-butyl­sulfin­yl)carbamo­yl]benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238995/
https://www.ncbi.nlm.nih.gov/pubmed/22199844
http://dx.doi.org/10.1107/S1600536811047027
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AT berrangerthierry ethyl2ntertbutylsulfinylcarbamoylbenzoate
AT grasemmanuel ethyl2ntertbutylsulfinylcarbamoylbenzoate

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