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2-Amino­benzoic acid–4-(pyridin-4-yl­disulfan­yl)pyridine (1/1)

The title 1:1 co-crystal, C(7)H(7)NO(2)·C(10)H(8)N(2)S(2), features a highly twisted 4-(pyridin-4-yldisulfan­yl)pyridine mol­ecule [dihedral angle between the pyridine rings = 89.06 (10)°]. A small twist is evident in the 2-amino­benzoic acid mol­ecule, with the C—C—C—O torsion angle being −7.7 (3)°...

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Autores principales: Arman, Hadi D., Kaulgud, Trupta, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239006/
https://www.ncbi.nlm.nih.gov/pubmed/22199855
http://dx.doi.org/10.1107/S1600536811048483
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author Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The title 1:1 co-crystal, C(7)H(7)NO(2)·C(10)H(8)N(2)S(2), features a highly twisted 4-(pyridin-4-yldisulfan­yl)pyridine mol­ecule [dihedral angle between the pyridine rings = 89.06 (10)°]. A small twist is evident in the 2-amino­benzoic acid mol­ecule, with the C—C—C—O torsion angle being −7.7 (3)°. An N—H⋯O hydrogen bond occurs in the 2-amino­benzoic acid mol­ecule. In the crystal, mol­ecules are linked by O—H⋯N and N—H⋯N hydrogen bonds into a supra­molecular chain along the b axis. These are connected into layers by π–π inter­actions occurring between pyridine rings [centroid–centroid distance = 3.8489 (15) Å]. The layers are connected along the a axis by C—H⋯O contacts. The crystal studied was a racemic twin.
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spelling pubmed-32390062011-12-23 2-Amino­benzoic acid–4-(pyridin-4-yl­disulfan­yl)pyridine (1/1) Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title 1:1 co-crystal, C(7)H(7)NO(2)·C(10)H(8)N(2)S(2), features a highly twisted 4-(pyridin-4-yldisulfan­yl)pyridine mol­ecule [dihedral angle between the pyridine rings = 89.06 (10)°]. A small twist is evident in the 2-amino­benzoic acid mol­ecule, with the C—C—C—O torsion angle being −7.7 (3)°. An N—H⋯O hydrogen bond occurs in the 2-amino­benzoic acid mol­ecule. In the crystal, mol­ecules are linked by O—H⋯N and N—H⋯N hydrogen bonds into a supra­molecular chain along the b axis. These are connected into layers by π–π inter­actions occurring between pyridine rings [centroid–centroid distance = 3.8489 (15) Å]. The layers are connected along the a axis by C—H⋯O contacts. The crystal studied was a racemic twin. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3239006/ /pubmed/22199855 http://dx.doi.org/10.1107/S1600536811048483 Text en © Arman et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
2-Amino­benzoic acid–4-(pyridin-4-yl­disulfan­yl)pyridine (1/1)
title 2-Amino­benzoic acid–4-(pyridin-4-yl­disulfan­yl)pyridine (1/1)
title_full 2-Amino­benzoic acid–4-(pyridin-4-yl­disulfan­yl)pyridine (1/1)
title_fullStr 2-Amino­benzoic acid–4-(pyridin-4-yl­disulfan­yl)pyridine (1/1)
title_full_unstemmed 2-Amino­benzoic acid–4-(pyridin-4-yl­disulfan­yl)pyridine (1/1)
title_short 2-Amino­benzoic acid–4-(pyridin-4-yl­disulfan­yl)pyridine (1/1)
title_sort 2-amino­benzoic acid–4-(pyridin-4-yl­disulfan­yl)pyridine (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239006/
https://www.ncbi.nlm.nih.gov/pubmed/22199855
http://dx.doi.org/10.1107/S1600536811048483
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