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2-Aminobenzoic acid–4-(pyridin-4-yldisulfanyl)pyridine (1/1)
The title 1:1 co-crystal, C(7)H(7)NO(2)·C(10)H(8)N(2)S(2), features a highly twisted 4-(pyridin-4-yldisulfanyl)pyridine molecule [dihedral angle between the pyridine rings = 89.06 (10)°]. A small twist is evident in the 2-aminobenzoic acid molecule, with the C—C—C—O torsion angle being −7.7 (3)°...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239006/ https://www.ncbi.nlm.nih.gov/pubmed/22199855 http://dx.doi.org/10.1107/S1600536811048483 |
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author | Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. |
author_facet | Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. |
author_sort | Arman, Hadi D. |
collection | PubMed |
description | The title 1:1 co-crystal, C(7)H(7)NO(2)·C(10)H(8)N(2)S(2), features a highly twisted 4-(pyridin-4-yldisulfanyl)pyridine molecule [dihedral angle between the pyridine rings = 89.06 (10)°]. A small twist is evident in the 2-aminobenzoic acid molecule, with the C—C—C—O torsion angle being −7.7 (3)°. An N—H⋯O hydrogen bond occurs in the 2-aminobenzoic acid molecule. In the crystal, molecules are linked by O—H⋯N and N—H⋯N hydrogen bonds into a supramolecular chain along the b axis. These are connected into layers by π–π interactions occurring between pyridine rings [centroid–centroid distance = 3.8489 (15) Å]. The layers are connected along the a axis by C—H⋯O contacts. The crystal studied was a racemic twin. |
format | Online Article Text |
id | pubmed-3239006 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32390062011-12-23 2-Aminobenzoic acid–4-(pyridin-4-yldisulfanyl)pyridine (1/1) Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title 1:1 co-crystal, C(7)H(7)NO(2)·C(10)H(8)N(2)S(2), features a highly twisted 4-(pyridin-4-yldisulfanyl)pyridine molecule [dihedral angle between the pyridine rings = 89.06 (10)°]. A small twist is evident in the 2-aminobenzoic acid molecule, with the C—C—C—O torsion angle being −7.7 (3)°. An N—H⋯O hydrogen bond occurs in the 2-aminobenzoic acid molecule. In the crystal, molecules are linked by O—H⋯N and N—H⋯N hydrogen bonds into a supramolecular chain along the b axis. These are connected into layers by π–π interactions occurring between pyridine rings [centroid–centroid distance = 3.8489 (15) Å]. The layers are connected along the a axis by C—H⋯O contacts. The crystal studied was a racemic twin. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3239006/ /pubmed/22199855 http://dx.doi.org/10.1107/S1600536811048483 Text en © Arman et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. 2-Aminobenzoic acid–4-(pyridin-4-yldisulfanyl)pyridine (1/1) |
title | 2-Aminobenzoic acid–4-(pyridin-4-yldisulfanyl)pyridine (1/1) |
title_full | 2-Aminobenzoic acid–4-(pyridin-4-yldisulfanyl)pyridine (1/1) |
title_fullStr | 2-Aminobenzoic acid–4-(pyridin-4-yldisulfanyl)pyridine (1/1) |
title_full_unstemmed | 2-Aminobenzoic acid–4-(pyridin-4-yldisulfanyl)pyridine (1/1) |
title_short | 2-Aminobenzoic acid–4-(pyridin-4-yldisulfanyl)pyridine (1/1) |
title_sort | 2-aminobenzoic acid–4-(pyridin-4-yldisulfanyl)pyridine (1/1) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239006/ https://www.ncbi.nlm.nih.gov/pubmed/22199855 http://dx.doi.org/10.1107/S1600536811048483 |
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