1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate

In the title compound, C(19)H(19)N(4)O(2) (+)·Cl(−)·C(2)H(3)N, the dihedral angle between the two phenyl rings is 69.57 (8)° while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N—H⋯Cl, C—H⋯O, C—H⋯Cl and C—H⋯N hydrogen bonds link the...

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Detalles Bibliográficos
Autores principales: Liao, Chuang-Yi, Lee, Hon Man
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239007/
https://www.ncbi.nlm.nih.gov/pubmed/22199856
http://dx.doi.org/10.1107/S1600536811048410
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author Liao, Chuang-Yi
Lee, Hon Man
author_facet Liao, Chuang-Yi
Lee, Hon Man
author_sort Liao, Chuang-Yi
collection PubMed
description In the title compound, C(19)H(19)N(4)O(2) (+)·Cl(−)·C(2)H(3)N, the dihedral angle between the two phenyl rings is 69.57 (8)° while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N—H⋯Cl, C—H⋯O, C—H⋯Cl and C—H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent mol­ecules into a two-dimensional hydrogen-bonded network parallel to (001); an intra­molecular C—H⋯O hydrogen bond is also observed.
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spelling pubmed-32390072011-12-23 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate Liao, Chuang-Yi Lee, Hon Man Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(19)N(4)O(2) (+)·Cl(−)·C(2)H(3)N, the dihedral angle between the two phenyl rings is 69.57 (8)° while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N—H⋯Cl, C—H⋯O, C—H⋯Cl and C—H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent mol­ecules into a two-dimensional hydrogen-bonded network parallel to (001); an intra­molecular C—H⋯O hydrogen bond is also observed. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3239007/ /pubmed/22199856 http://dx.doi.org/10.1107/S1600536811048410 Text en © Liao and Lee 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liao, Chuang-Yi
Lee, Hon Man
1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate
title 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate
title_full 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate
title_fullStr 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate
title_full_unstemmed 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate
title_short 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate
title_sort 1,3-bis(2-anilino-2-oxoeth­yl)-1h-imidazol-3-ium chloride acetonitrile monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239007/
https://www.ncbi.nlm.nih.gov/pubmed/22199856
http://dx.doi.org/10.1107/S1600536811048410
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AT leehonman 13bis2anilino2oxoethyl1himidazol3iumchlorideacetonitrilemonosolvate

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