N′-[(E)-1-(5-Bromo-2-hy­droxy­phen­yl)ethyl­idene]-2-chloro­benzohydrazide

The title compound, C(15)H(12)BrClN(2)O(2), was synthesized by the condensation of 1-(5-bromo-2-hy­droxy­phen­yl)ethanone with 2-chloro­benzohydrazide in anhydrous ethanol. The Schiff base mol­ecule displays a trans configuration with respect to the C=N double bond. The dihedral angle between the tw...

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Autor principal: Chang, Jian-Guo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239010/
https://www.ncbi.nlm.nih.gov/pubmed/22199859
http://dx.doi.org/10.1107/S1600536811048495
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author Chang, Jian-Guo
author_facet Chang, Jian-Guo
author_sort Chang, Jian-Guo
collection PubMed
description The title compound, C(15)H(12)BrClN(2)O(2), was synthesized by the condensation of 1-(5-bromo-2-hy­droxy­phen­yl)ethanone with 2-chloro­benzohydrazide in anhydrous ethanol. The Schiff base mol­ecule displays a trans configuration with respect to the C=N double bond. The dihedral angle between the two benzene rings is 13.74 (3)°. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N and the crystal structure by inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-32390102011-12-23 N′-[(E)-1-(5-Bromo-2-hy­droxy­phen­yl)ethyl­idene]-2-chloro­benzohydrazide Chang, Jian-Guo Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)BrClN(2)O(2), was synthesized by the condensation of 1-(5-bromo-2-hy­droxy­phen­yl)ethanone with 2-chloro­benzohydrazide in anhydrous ethanol. The Schiff base mol­ecule displays a trans configuration with respect to the C=N double bond. The dihedral angle between the two benzene rings is 13.74 (3)°. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N and the crystal structure by inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3239010/ /pubmed/22199859 http://dx.doi.org/10.1107/S1600536811048495 Text en © Jian-Guo Chang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chang, Jian-Guo
N′-[(E)-1-(5-Bromo-2-hy­droxy­phen­yl)ethyl­idene]-2-chloro­benzohydrazide
title N′-[(E)-1-(5-Bromo-2-hy­droxy­phen­yl)ethyl­idene]-2-chloro­benzohydrazide
title_full N′-[(E)-1-(5-Bromo-2-hy­droxy­phen­yl)ethyl­idene]-2-chloro­benzohydrazide
title_fullStr N′-[(E)-1-(5-Bromo-2-hy­droxy­phen­yl)ethyl­idene]-2-chloro­benzohydrazide
title_full_unstemmed N′-[(E)-1-(5-Bromo-2-hy­droxy­phen­yl)ethyl­idene]-2-chloro­benzohydrazide
title_short N′-[(E)-1-(5-Bromo-2-hy­droxy­phen­yl)ethyl­idene]-2-chloro­benzohydrazide
title_sort n′-[(e)-1-(5-bromo-2-hy­droxy­phen­yl)ethyl­idene]-2-chloro­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239010/
https://www.ncbi.nlm.nih.gov/pubmed/22199859
http://dx.doi.org/10.1107/S1600536811048495
work_keys_str_mv AT changjianguo ne15bromo2hydroxyphenylethylidene2chlorobenzohydrazide

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