5,8-Dibromo-15-nitro-2,11-dithia­[3.3]paracyclo­phane

In the title compound [systematic name: 13,15-dibromo-6-nitro-3,10-dithia­tricyclo­[10.2.2.2(5,8)]octa­deca-1(14),5,7,12,15,17-hexa­ene], C(16)H(13)Br(2)NO(2)S(2), the dihedral angle between the two benzene rings is 0.93 (2)°. The crystal structure is stabilized by weak π–π inter­molecular inter­act...

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Detalles Bibliográficos
Autores principales: Hu, Fang, Chen, Zhi-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239012/
https://www.ncbi.nlm.nih.gov/pubmed/22199861
http://dx.doi.org/10.1107/S1600536811048434
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author Hu, Fang
Chen, Zhi-Ming
author_facet Hu, Fang
Chen, Zhi-Ming
author_sort Hu, Fang
collection PubMed
description In the title compound [systematic name: 13,15-dibromo-6-nitro-3,10-dithia­tricyclo­[10.2.2.2(5,8)]octa­deca-1(14),5,7,12,15,17-hexa­ene], C(16)H(13)Br(2)NO(2)S(2), the dihedral angle between the two benzene rings is 0.93 (2)°. The crystal structure is stabilized by weak π–π inter­molecular inter­actions [centroid–centroid distance = 3.286 (5) Å]. One S atom and the H atoms on neighboring C atoms are disordered over two sets of sites (occupancy ratios: S = 0.91:0.09 and H = 0.93:0.07).
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spelling pubmed-32390122011-12-23 5,8-Dibromo-15-nitro-2,11-dithia­[3.3]paracyclo­phane Hu, Fang Chen, Zhi-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound [systematic name: 13,15-dibromo-6-nitro-3,10-dithia­tricyclo­[10.2.2.2(5,8)]octa­deca-1(14),5,7,12,15,17-hexa­ene], C(16)H(13)Br(2)NO(2)S(2), the dihedral angle between the two benzene rings is 0.93 (2)°. The crystal structure is stabilized by weak π–π inter­molecular inter­actions [centroid–centroid distance = 3.286 (5) Å]. One S atom and the H atoms on neighboring C atoms are disordered over two sets of sites (occupancy ratios: S = 0.91:0.09 and H = 0.93:0.07). International Union of Crystallography 2011-11-19 /pmc/articles/PMC3239012/ /pubmed/22199861 http://dx.doi.org/10.1107/S1600536811048434 Text en © Hu and Chen 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hu, Fang
Chen, Zhi-Ming
5,8-Dibromo-15-nitro-2,11-dithia­[3.3]paracyclo­phane
title 5,8-Dibromo-15-nitro-2,11-dithia­[3.3]paracyclo­phane
title_full 5,8-Dibromo-15-nitro-2,11-dithia­[3.3]paracyclo­phane
title_fullStr 5,8-Dibromo-15-nitro-2,11-dithia­[3.3]paracyclo­phane
title_full_unstemmed 5,8-Dibromo-15-nitro-2,11-dithia­[3.3]paracyclo­phane
title_short 5,8-Dibromo-15-nitro-2,11-dithia­[3.3]paracyclo­phane
title_sort 5,8-dibromo-15-nitro-2,11-dithia­[3.3]paracyclo­phane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239012/
https://www.ncbi.nlm.nih.gov/pubmed/22199861
http://dx.doi.org/10.1107/S1600536811048434
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