5-(4,4′′-Difluoro-5′-hy­droxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-(morpholin-4-ylmeth­yl)-1,3,4-oxadiazole-2(3H)-thione

In the title compound, C(25)H(21)F(2)N(3)O(3)S, the morpholine ring adopts a chair conformation. The 1,3,4-oxadiazole-2(3H)-thione group makes dihedral angles of 78.69 (8), 53.56 (7) and 55.30 (9)° with the benzene rings. In the crystal, O—H⋯O, C—H⋯S and C—H⋯F hydrogen bonds linked the mol­ecules in...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Arshad, Suhana, Samshuddin, S., Narayana, B., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239015/
https://www.ncbi.nlm.nih.gov/pubmed/22199864
http://dx.doi.org/10.1107/S1600536811048471
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author Fun, Hoong-Kun
Arshad, Suhana
Samshuddin, S.
Narayana, B.
Sarojini, B. K.
author_facet Fun, Hoong-Kun
Arshad, Suhana
Samshuddin, S.
Narayana, B.
Sarojini, B. K.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(25)H(21)F(2)N(3)O(3)S, the morpholine ring adopts a chair conformation. The 1,3,4-oxadiazole-2(3H)-thione group makes dihedral angles of 78.69 (8), 53.56 (7) and 55.30 (9)° with the benzene rings. In the crystal, O—H⋯O, C—H⋯S and C—H⋯F hydrogen bonds linked the mol­ecules into layers lying parallel to the ab plane. Weak C—H⋯π inter­actions also occur.
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spelling pubmed-32390152011-12-23 5-(4,4′′-Difluoro-5′-hy­droxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-(morpholin-4-ylmeth­yl)-1,3,4-oxadiazole-2(3H)-thione Fun, Hoong-Kun Arshad, Suhana Samshuddin, S. Narayana, B. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(21)F(2)N(3)O(3)S, the morpholine ring adopts a chair conformation. The 1,3,4-oxadiazole-2(3H)-thione group makes dihedral angles of 78.69 (8), 53.56 (7) and 55.30 (9)° with the benzene rings. In the crystal, O—H⋯O, C—H⋯S and C—H⋯F hydrogen bonds linked the mol­ecules into layers lying parallel to the ab plane. Weak C—H⋯π inter­actions also occur. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3239015/ /pubmed/22199864 http://dx.doi.org/10.1107/S1600536811048471 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Arshad, Suhana
Samshuddin, S.
Narayana, B.
Sarojini, B. K.
5-(4,4′′-Difluoro-5′-hy­droxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-(morpholin-4-ylmeth­yl)-1,3,4-oxadiazole-2(3H)-thione
title 5-(4,4′′-Difluoro-5′-hy­droxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-(morpholin-4-ylmeth­yl)-1,3,4-oxadiazole-2(3H)-thione
title_full 5-(4,4′′-Difluoro-5′-hy­droxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-(morpholin-4-ylmeth­yl)-1,3,4-oxadiazole-2(3H)-thione
title_fullStr 5-(4,4′′-Difluoro-5′-hy­droxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-(morpholin-4-ylmeth­yl)-1,3,4-oxadiazole-2(3H)-thione
title_full_unstemmed 5-(4,4′′-Difluoro-5′-hy­droxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-(morpholin-4-ylmeth­yl)-1,3,4-oxadiazole-2(3H)-thione
title_short 5-(4,4′′-Difluoro-5′-hy­droxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-(morpholin-4-ylmeth­yl)-1,3,4-oxadiazole-2(3H)-thione
title_sort 5-(4,4′′-difluoro-5′-hy­droxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-(morpholin-4-ylmeth­yl)-1,3,4-oxadiazole-2(3h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239015/
https://www.ncbi.nlm.nih.gov/pubmed/22199864
http://dx.doi.org/10.1107/S1600536811048471
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