2,4-Dibromo-6-[(quinolin-8-yl­amino)­methyl­idene]cyclo­hexa-2,4-dien-1-one monohydrate

In the title compound, C(16)H(10)Br(2)N(2)O·H(2)O, bifurcated intra­molecular N—H⋯(N,O) hydrogen bonding defines the essential planarity of the main mol­ecule: the dihedral angle between the quinoline and benzene rings is 7.53 (8)°. Inter­molecular O—H⋯O and weak C—H⋯O hydrogen bonds consolidate the...

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Detalles Bibliográficos
Autores principales: Kawamoto, Keisuke, Shibahara, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239023/
https://www.ncbi.nlm.nih.gov/pubmed/22199871
http://dx.doi.org/10.1107/S1600536811048793
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author Kawamoto, Keisuke
Shibahara, Takashi
author_facet Kawamoto, Keisuke
Shibahara, Takashi
author_sort Kawamoto, Keisuke
collection PubMed
description In the title compound, C(16)H(10)Br(2)N(2)O·H(2)O, bifurcated intra­molecular N—H⋯(N,O) hydrogen bonding defines the essential planarity of the main mol­ecule: the dihedral angle between the quinoline and benzene rings is 7.53 (8)°. Inter­molecular O—H⋯O and weak C—H⋯O hydrogen bonds consolidate the crystal packing, which exhibits π–π inter­actions with a distance of 3.588 (1) Å between the centroids of the aromatic rings and short Br⋯Br contacts of 3.5757 (6) Å.
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spelling pubmed-32390232011-12-23 2,4-Dibromo-6-[(quinolin-8-yl­amino)­methyl­idene]cyclo­hexa-2,4-dien-1-one monohydrate Kawamoto, Keisuke Shibahara, Takashi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(10)Br(2)N(2)O·H(2)O, bifurcated intra­molecular N—H⋯(N,O) hydrogen bonding defines the essential planarity of the main mol­ecule: the dihedral angle between the quinoline and benzene rings is 7.53 (8)°. Inter­molecular O—H⋯O and weak C—H⋯O hydrogen bonds consolidate the crystal packing, which exhibits π–π inter­actions with a distance of 3.588 (1) Å between the centroids of the aromatic rings and short Br⋯Br contacts of 3.5757 (6) Å. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3239023/ /pubmed/22199871 http://dx.doi.org/10.1107/S1600536811048793 Text en © Kawamoto and Shibahara 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kawamoto, Keisuke
Shibahara, Takashi
2,4-Dibromo-6-[(quinolin-8-yl­amino)­methyl­idene]cyclo­hexa-2,4-dien-1-one monohydrate
title 2,4-Dibromo-6-[(quinolin-8-yl­amino)­methyl­idene]cyclo­hexa-2,4-dien-1-one monohydrate
title_full 2,4-Dibromo-6-[(quinolin-8-yl­amino)­methyl­idene]cyclo­hexa-2,4-dien-1-one monohydrate
title_fullStr 2,4-Dibromo-6-[(quinolin-8-yl­amino)­methyl­idene]cyclo­hexa-2,4-dien-1-one monohydrate
title_full_unstemmed 2,4-Dibromo-6-[(quinolin-8-yl­amino)­methyl­idene]cyclo­hexa-2,4-dien-1-one monohydrate
title_short 2,4-Dibromo-6-[(quinolin-8-yl­amino)­methyl­idene]cyclo­hexa-2,4-dien-1-one monohydrate
title_sort 2,4-dibromo-6-[(quinolin-8-yl­amino)­methyl­idene]cyclo­hexa-2,4-dien-1-one monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239023/
https://www.ncbi.nlm.nih.gov/pubmed/22199871
http://dx.doi.org/10.1107/S1600536811048793
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