8-Acetyl-4-methyl-2-oxo-2H-chromen-7-yl acetate

In the title compound, C(14)H(12)O(5), the benzopyran-2-one ring system is approximately planar [maximum deviation = 0.018 (1) Å]; the mean plane is oriented at dihedral angles of 52.26 (11) and 72.92 (7)°, respectively, to the acetyl and acet­oxy groups. In the crystal, π–π stacking is observed bet...

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Detalles Bibliográficos
Autores principales: Yang, Shu-Ping, Han, Li-Jun, He, Xin-Ran, Chen, Li-Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239025/
https://www.ncbi.nlm.nih.gov/pubmed/22199873
http://dx.doi.org/10.1107/S1600536811048835
Descripción
Sumario:In the title compound, C(14)H(12)O(5), the benzopyran-2-one ring system is approximately planar [maximum deviation = 0.018 (1) Å]; the mean plane is oriented at dihedral angles of 52.26 (11) and 72.92 (7)°, respectively, to the acetyl and acet­oxy groups. In the crystal, π–π stacking is observed between parallel benzene rings of adjacent mol­ecules, the centroid–centroid distance being 3.6774 (17) Å. Inter­molecular weak C—H⋯O hydrogen bonding, and C=O⋯C=O [O⋯C = 3.058 (3) Å] and C=O⋯π [O⋯centroid = 3.328 (2) Å] inter­actions occur in the crystal structure.

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