(2R)-4-[(9H-Fluoren-9-ylmeth­oxy)carbon­yl]-2-methyl­piperazin-1-ium chloride

The synthesis of the title salt, C(20)H(23)N(2)O(2) (+)·Cl(−), was carried out with a precursor of known absolute configuration (R) and the X-ray analysis confirmed that the product retained the absolute configuration. In the crystal, the dominant packing motif is a chain running along [010] generat...

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Detalles Bibliográficos
Autores principales: Ertan, Anne, Sharma, Parhalad, Nagaraju, Dokka, Deepthi, K., Manjunatha, Sulur G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239028/
https://www.ncbi.nlm.nih.gov/pubmed/22199876
http://dx.doi.org/10.1107/S1600536811048306
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author Ertan, Anne
Sharma, Parhalad
Nagaraju, Dokka
Deepthi, K.
Manjunatha, Sulur G.
author_facet Ertan, Anne
Sharma, Parhalad
Nagaraju, Dokka
Deepthi, K.
Manjunatha, Sulur G.
author_sort Ertan, Anne
collection PubMed
description The synthesis of the title salt, C(20)H(23)N(2)O(2) (+)·Cl(−), was carried out with a precursor of known absolute configuration (R) and the X-ray analysis confirmed that the product retained the absolute configuration. In the crystal, the dominant packing motif is a chain running along [010] generated by N—H⋯Cl hydrogen bonding. C—H⋯O and C—H⋯Cl inter­actions are also observed.
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spelling pubmed-32390282011-12-23 (2R)-4-[(9H-Fluoren-9-ylmeth­oxy)carbon­yl]-2-methyl­piperazin-1-ium chloride Ertan, Anne Sharma, Parhalad Nagaraju, Dokka Deepthi, K. Manjunatha, Sulur G. Acta Crystallogr Sect E Struct Rep Online Organic Papers The synthesis of the title salt, C(20)H(23)N(2)O(2) (+)·Cl(−), was carried out with a precursor of known absolute configuration (R) and the X-ray analysis confirmed that the product retained the absolute configuration. In the crystal, the dominant packing motif is a chain running along [010] generated by N—H⋯Cl hydrogen bonding. C—H⋯O and C—H⋯Cl inter­actions are also observed. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3239028/ /pubmed/22199876 http://dx.doi.org/10.1107/S1600536811048306 Text en © Ertan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ertan, Anne
Sharma, Parhalad
Nagaraju, Dokka
Deepthi, K.
Manjunatha, Sulur G.
(2R)-4-[(9H-Fluoren-9-ylmeth­oxy)carbon­yl]-2-methyl­piperazin-1-ium chloride
title (2R)-4-[(9H-Fluoren-9-ylmeth­oxy)carbon­yl]-2-methyl­piperazin-1-ium chloride
title_full (2R)-4-[(9H-Fluoren-9-ylmeth­oxy)carbon­yl]-2-methyl­piperazin-1-ium chloride
title_fullStr (2R)-4-[(9H-Fluoren-9-ylmeth­oxy)carbon­yl]-2-methyl­piperazin-1-ium chloride
title_full_unstemmed (2R)-4-[(9H-Fluoren-9-ylmeth­oxy)carbon­yl]-2-methyl­piperazin-1-ium chloride
title_short (2R)-4-[(9H-Fluoren-9-ylmeth­oxy)carbon­yl]-2-methyl­piperazin-1-ium chloride
title_sort (2r)-4-[(9h-fluoren-9-ylmeth­oxy)carbon­yl]-2-methyl­piperazin-1-ium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239028/
https://www.ncbi.nlm.nih.gov/pubmed/22199876
http://dx.doi.org/10.1107/S1600536811048306
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