[1,4-Phenyl­enebis(methyl­ene)]bis­(tri­phenyl­phospho­nium) bis­(tetra­fluoro­borate)

The crystal structure of the title salt, C(44)H(38)P(2) (2+)2BF(4) (−), consists of discrete dications inter­laced with the BF(4) (−) counter-ions. In each cation, both phospho­nium groups lie on the same side of the plane of the central benzene ring. The tetra­fluoro­borate anions are involved in i...

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Detalles Bibliográficos
Autores principales: Ibrahim, Hamisu, Koorbanally, Neil, Ramjugernath, Deresh, Bala, Muhammad D., Nyamori, Vincent O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239032/
https://www.ncbi.nlm.nih.gov/pubmed/22199880
http://dx.doi.org/10.1107/S1600536811048975
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author Ibrahim, Hamisu
Koorbanally, Neil
Ramjugernath, Deresh
Bala, Muhammad D.
Nyamori, Vincent O.
author_facet Ibrahim, Hamisu
Koorbanally, Neil
Ramjugernath, Deresh
Bala, Muhammad D.
Nyamori, Vincent O.
author_sort Ibrahim, Hamisu
collection PubMed
description The crystal structure of the title salt, C(44)H(38)P(2) (2+)2BF(4) (−), consists of discrete dications inter­laced with the BF(4) (−) counter-ions. In each cation, both phospho­nium groups lie on the same side of the plane of the central benzene ring. The tetra­fluoro­borate anions are involved in intensive thermal motion, thus some B—F bond lengths [range 1.329 (6) to 1.391 (6) Å] deviate significantly from their standard values.
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spelling pubmed-32390322011-12-23 [1,4-Phenyl­enebis(methyl­ene)]bis­(tri­phenyl­phospho­nium) bis­(tetra­fluoro­borate) Ibrahim, Hamisu Koorbanally, Neil Ramjugernath, Deresh Bala, Muhammad D. Nyamori, Vincent O. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title salt, C(44)H(38)P(2) (2+)2BF(4) (−), consists of discrete dications inter­laced with the BF(4) (−) counter-ions. In each cation, both phospho­nium groups lie on the same side of the plane of the central benzene ring. The tetra­fluoro­borate anions are involved in intensive thermal motion, thus some B—F bond lengths [range 1.329 (6) to 1.391 (6) Å] deviate significantly from their standard values. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3239032/ /pubmed/22199880 http://dx.doi.org/10.1107/S1600536811048975 Text en © Ibrahim et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ibrahim, Hamisu
Koorbanally, Neil
Ramjugernath, Deresh
Bala, Muhammad D.
Nyamori, Vincent O.
[1,4-Phenyl­enebis(methyl­ene)]bis­(tri­phenyl­phospho­nium) bis­(tetra­fluoro­borate)
title [1,4-Phenyl­enebis(methyl­ene)]bis­(tri­phenyl­phospho­nium) bis­(tetra­fluoro­borate)
title_full [1,4-Phenyl­enebis(methyl­ene)]bis­(tri­phenyl­phospho­nium) bis­(tetra­fluoro­borate)
title_fullStr [1,4-Phenyl­enebis(methyl­ene)]bis­(tri­phenyl­phospho­nium) bis­(tetra­fluoro­borate)
title_full_unstemmed [1,4-Phenyl­enebis(methyl­ene)]bis­(tri­phenyl­phospho­nium) bis­(tetra­fluoro­borate)
title_short [1,4-Phenyl­enebis(methyl­ene)]bis­(tri­phenyl­phospho­nium) bis­(tetra­fluoro­borate)
title_sort [1,4-phenyl­enebis(methyl­ene)]bis­(tri­phenyl­phospho­nium) bis­(tetra­fluoro­borate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239032/
https://www.ncbi.nlm.nih.gov/pubmed/22199880
http://dx.doi.org/10.1107/S1600536811048975
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