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4-Chloroanilinium perchlorate–18-crown-16 (1/1)
In the title compound, C(6)H(7)ClN(+)·ClO(4) (−)·C(12)H(24)O(6), the cation forms a 1:1 complex with the crown ether, viz [C(6)H(7)ClN-(18-crown-6)](+), in which the –NH(3) (+) unit nests in the crown and interacts with it through bifurcated N—H⋯O hydrogen bonding. All constituents of the structure...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239039/ https://www.ncbi.nlm.nih.gov/pubmed/22199887 http://dx.doi.org/10.1107/S1600536811048859 |
| _version_ | 1782219110820610048 |
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| author | Yu, Chun-Hua |
| author_facet | Yu, Chun-Hua |
| author_sort | Yu, Chun-Hua |
| collection | PubMed |
| description | In the title compound, C(6)H(7)ClN(+)·ClO(4) (−)·C(12)H(24)O(6), the cation forms a 1:1 complex with the crown ether, viz [C(6)H(7)ClN-(18-crown-6)](+), in which the –NH(3) (+) unit nests in the crown and interacts with it through bifurcated N—H⋯O hydrogen bonding. All constituents of the structure have crystallographically imposed mirror symmetry except for the H atoms of the –NH(3) (+) group which are disordered across the mirror. |
| format | Online Article Text |
| id | pubmed-3239039 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32390392011-12-23 4-Chloroanilinium perchlorate–18-crown-16 (1/1) Yu, Chun-Hua Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(7)ClN(+)·ClO(4) (−)·C(12)H(24)O(6), the cation forms a 1:1 complex with the crown ether, viz [C(6)H(7)ClN-(18-crown-6)](+), in which the –NH(3) (+) unit nests in the crown and interacts with it through bifurcated N—H⋯O hydrogen bonding. All constituents of the structure have crystallographically imposed mirror symmetry except for the H atoms of the –NH(3) (+) group which are disordered across the mirror. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3239039/ /pubmed/22199887 http://dx.doi.org/10.1107/S1600536811048859 Text en © Chun-Hua Yu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Yu, Chun-Hua 4-Chloroanilinium perchlorate–18-crown-16 (1/1) |
| title | 4-Chloroanilinium perchlorate–18-crown-16 (1/1) |
| title_full | 4-Chloroanilinium perchlorate–18-crown-16 (1/1) |
| title_fullStr | 4-Chloroanilinium perchlorate–18-crown-16 (1/1) |
| title_full_unstemmed | 4-Chloroanilinium perchlorate–18-crown-16 (1/1) |
| title_short | 4-Chloroanilinium perchlorate–18-crown-16 (1/1) |
| title_sort | 4-chloroanilinium perchlorate–18-crown-16 (1/1) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239039/ https://www.ncbi.nlm.nih.gov/pubmed/22199887 http://dx.doi.org/10.1107/S1600536811048859 |
| work_keys_str_mv | AT yuchunhua 4chloroaniliniumperchlorate18crown1611 |