N,N′-Dicyclo­pentyl-N′′,N′′-dimethyl­phospho­ric triamide

The P atom in the title mol­ecule, C(12)H(26)N(3)OP, has a distorted tetra­hedral configuration: its bond angles lie in the range 101.1 (2)–119.1 (2)°. The P—N bonds to the two cyclo­pentyl­amido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an an...

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Detalles Bibliográficos
Autores principales: Raissi Shabari, Akbar, Pourayoubi, Mehrdad, Ghoreishi, Farnaz, Vahdani, Banafsheh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239040/
https://www.ncbi.nlm.nih.gov/pubmed/22199888
http://dx.doi.org/10.1107/S1600536811048549
Descripción
Sumario:The P atom in the title mol­ecule, C(12)H(26)N(3)OP, has a distorted tetra­hedral configuration: its bond angles lie in the range 101.1 (2)–119.1 (2)°. The P—N bonds to the two cyclo­pentyl­amido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an anti orientation of the lone electron pair of the corresponding N atom relative to the P=O bond. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different inter­molecular N—H⋯O(P) hydrogen bonds, building R (2) (2)(8) rings that are further linked into chains along [001].

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