N,N′-Dicyclo­pentyl-N′′,N′′-dimethyl­phospho­ric triamide

The P atom in the title mol­ecule, C(12)H(26)N(3)OP, has a distorted tetra­hedral configuration: its bond angles lie in the range 101.1 (2)–119.1 (2)°. The P—N bonds to the two cyclo­pentyl­amido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an an...

Descripción completa

Detalles Bibliográficos
Autores principales: Raissi Shabari, Akbar, Pourayoubi, Mehrdad, Ghoreishi, Farnaz, Vahdani, Banafsheh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239040/
https://www.ncbi.nlm.nih.gov/pubmed/22199888
http://dx.doi.org/10.1107/S1600536811048549
_version_ 1782219111050248192
author Raissi Shabari, Akbar
Pourayoubi, Mehrdad
Ghoreishi, Farnaz
Vahdani, Banafsheh
author_facet Raissi Shabari, Akbar
Pourayoubi, Mehrdad
Ghoreishi, Farnaz
Vahdani, Banafsheh
author_sort Raissi Shabari, Akbar
collection PubMed
description The P atom in the title mol­ecule, C(12)H(26)N(3)OP, has a distorted tetra­hedral configuration: its bond angles lie in the range 101.1 (2)–119.1 (2)°. The P—N bonds to the two cyclo­pentyl­amido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an anti orientation of the lone electron pair of the corresponding N atom relative to the P=O bond. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different inter­molecular N—H⋯O(P) hydrogen bonds, building R (2) (2)(8) rings that are further linked into chains along [001].
format Online
Article
Text
id pubmed-3239040
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32390402011-12-23 N,N′-Dicyclo­pentyl-N′′,N′′-dimethyl­phospho­ric triamide Raissi Shabari, Akbar Pourayoubi, Mehrdad Ghoreishi, Farnaz Vahdani, Banafsheh Acta Crystallogr Sect E Struct Rep Online Organic Papers The P atom in the title mol­ecule, C(12)H(26)N(3)OP, has a distorted tetra­hedral configuration: its bond angles lie in the range 101.1 (2)–119.1 (2)°. The P—N bonds to the two cyclo­pentyl­amido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an anti orientation of the lone electron pair of the corresponding N atom relative to the P=O bond. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different inter­molecular N—H⋯O(P) hydrogen bonds, building R (2) (2)(8) rings that are further linked into chains along [001]. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3239040/ /pubmed/22199888 http://dx.doi.org/10.1107/S1600536811048549 Text en © Raissi Shabari et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Raissi Shabari, Akbar
Pourayoubi, Mehrdad
Ghoreishi, Farnaz
Vahdani, Banafsheh
N,N′-Dicyclo­pentyl-N′′,N′′-dimethyl­phospho­ric triamide
title N,N′-Dicyclo­pentyl-N′′,N′′-dimethyl­phospho­ric triamide
title_full N,N′-Dicyclo­pentyl-N′′,N′′-dimethyl­phospho­ric triamide
title_fullStr N,N′-Dicyclo­pentyl-N′′,N′′-dimethyl­phospho­ric triamide
title_full_unstemmed N,N′-Dicyclo­pentyl-N′′,N′′-dimethyl­phospho­ric triamide
title_short N,N′-Dicyclo­pentyl-N′′,N′′-dimethyl­phospho­ric triamide
title_sort n,n′-dicyclo­pentyl-n′′,n′′-dimethyl­phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239040/
https://www.ncbi.nlm.nih.gov/pubmed/22199888
http://dx.doi.org/10.1107/S1600536811048549
work_keys_str_mv AT raissishabariakbar nndicyclopentylnndimethylphosphorictriamide
AT pourayoubimehrdad nndicyclopentylnndimethylphosphorictriamide
AT ghoreishifarnaz nndicyclopentylnndimethylphosphorictriamide
AT vahdanibanafsheh nndicyclopentylnndimethylphosphorictriamide

Ejemplares similares