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N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenylacetyl)phosphoric triamide
The P atom in the title molecule, C(24)H(28)N(3)O(2)P, is in a distorted tetrahedral P(=O)(N)(N)(2) environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other and the N atoms have sp (2) character. The P—N bonds in the P(O)[N(CH(3))(CH(2)C(6)H(5))](2) unit...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239060/ https://www.ncbi.nlm.nih.gov/pubmed/22199908 http://dx.doi.org/10.1107/S1600536811049178 |
Sumario: | The P atom in the title molecule, C(24)H(28)N(3)O(2)P, is in a distorted tetrahedral P(=O)(N)(N)(2) environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other and the N atoms have sp (2) character. The P—N bonds in the P(O)[N(CH(3))(CH(2)C(6)H(5))](2) unit are shorter than the P—N bond in the C(=O)NHP(=O) fragment. An intramolecular C—H⋯O hydrogen bond occurs. In the crystal, pairs of P=O⋯H—N hydrogen bonds form centrosymmetric dimers. C—H⋯O contacts are also observed. Four C atoms of two benzene rings are disordered over two alternative sites with an occupancy ratio of 0.523 (12):0.427 (12). |
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