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N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenyl­acet­yl)phospho­ric triamide

The P atom in the title mol­ecule, C(24)H(28)N(3)O(2)P, is in a distorted tetra­hedral P(=O)(N)(N)(2) environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other and the N atoms have sp (2) character. The P—N bonds in the P(O)[N(CH(3))(CH(2)C(6)H(5))](2) unit...

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Autores principales: Pourayoubi, Mehrdad, Shoghpour, Samad, Torre-Fernández, Laura, García-Granda, Santiago
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239060/
https://www.ncbi.nlm.nih.gov/pubmed/22199908
http://dx.doi.org/10.1107/S1600536811049178
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author Pourayoubi, Mehrdad
Shoghpour, Samad
Torre-Fernández, Laura
García-Granda, Santiago
author_facet Pourayoubi, Mehrdad
Shoghpour, Samad
Torre-Fernández, Laura
García-Granda, Santiago
author_sort Pourayoubi, Mehrdad
collection PubMed
description The P atom in the title mol­ecule, C(24)H(28)N(3)O(2)P, is in a distorted tetra­hedral P(=O)(N)(N)(2) environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other and the N atoms have sp (2) character. The P—N bonds in the P(O)[N(CH(3))(CH(2)C(6)H(5))](2) unit are shorter than the P—N bond in the C(=O)NHP(=O) fragment. An intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, pairs of P=O⋯H—N hydrogen bonds form centrosymmetric dimers. C—H⋯O contacts are also observed. Four C atoms of two benzene rings are disordered over two alternative sites with an occupancy ratio of 0.523 (12):0.427 (12).
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spelling pubmed-32390602011-12-23 N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenyl­acet­yl)phospho­ric triamide Pourayoubi, Mehrdad Shoghpour, Samad Torre-Fernández, Laura García-Granda, Santiago Acta Crystallogr Sect E Struct Rep Online Organic Papers The P atom in the title mol­ecule, C(24)H(28)N(3)O(2)P, is in a distorted tetra­hedral P(=O)(N)(N)(2) environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other and the N atoms have sp (2) character. The P—N bonds in the P(O)[N(CH(3))(CH(2)C(6)H(5))](2) unit are shorter than the P—N bond in the C(=O)NHP(=O) fragment. An intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, pairs of P=O⋯H—N hydrogen bonds form centrosymmetric dimers. C—H⋯O contacts are also observed. Four C atoms of two benzene rings are disordered over two alternative sites with an occupancy ratio of 0.523 (12):0.427 (12). International Union of Crystallography 2011-11-25 /pmc/articles/PMC3239060/ /pubmed/22199908 http://dx.doi.org/10.1107/S1600536811049178 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Shoghpour, Samad
Torre-Fernández, Laura
García-Granda, Santiago
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenyl­acet­yl)phospho­ric triamide
title N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenyl­acet­yl)phospho­ric triamide
title_full N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenyl­acet­yl)phospho­ric triamide
title_fullStr N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenyl­acet­yl)phospho­ric triamide
title_full_unstemmed N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenyl­acet­yl)phospho­ric triamide
title_short N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenyl­acet­yl)phospho­ric triamide
title_sort n,n′-dibenzyl-n,n′-dimethyl-n′′-(2-phenyl­acet­yl)phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239060/
https://www.ncbi.nlm.nih.gov/pubmed/22199908
http://dx.doi.org/10.1107/S1600536811049178
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