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N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenylacetyl)phosphoric triamide
The P atom in the title molecule, C(24)H(28)N(3)O(2)P, is in a distorted tetrahedral P(=O)(N)(N)(2) environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other and the N atoms have sp (2) character. The P—N bonds in the P(O)[N(CH(3))(CH(2)C(6)H(5))](2) unit...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239060/ https://www.ncbi.nlm.nih.gov/pubmed/22199908 http://dx.doi.org/10.1107/S1600536811049178 |
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author | Pourayoubi, Mehrdad Shoghpour, Samad Torre-Fernández, Laura García-Granda, Santiago |
author_facet | Pourayoubi, Mehrdad Shoghpour, Samad Torre-Fernández, Laura García-Granda, Santiago |
author_sort | Pourayoubi, Mehrdad |
collection | PubMed |
description | The P atom in the title molecule, C(24)H(28)N(3)O(2)P, is in a distorted tetrahedral P(=O)(N)(N)(2) environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other and the N atoms have sp (2) character. The P—N bonds in the P(O)[N(CH(3))(CH(2)C(6)H(5))](2) unit are shorter than the P—N bond in the C(=O)NHP(=O) fragment. An intramolecular C—H⋯O hydrogen bond occurs. In the crystal, pairs of P=O⋯H—N hydrogen bonds form centrosymmetric dimers. C—H⋯O contacts are also observed. Four C atoms of two benzene rings are disordered over two alternative sites with an occupancy ratio of 0.523 (12):0.427 (12). |
format | Online Article Text |
id | pubmed-3239060 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32390602011-12-23 N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenylacetyl)phosphoric triamide Pourayoubi, Mehrdad Shoghpour, Samad Torre-Fernández, Laura García-Granda, Santiago Acta Crystallogr Sect E Struct Rep Online Organic Papers The P atom in the title molecule, C(24)H(28)N(3)O(2)P, is in a distorted tetrahedral P(=O)(N)(N)(2) environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other and the N atoms have sp (2) character. The P—N bonds in the P(O)[N(CH(3))(CH(2)C(6)H(5))](2) unit are shorter than the P—N bond in the C(=O)NHP(=O) fragment. An intramolecular C—H⋯O hydrogen bond occurs. In the crystal, pairs of P=O⋯H—N hydrogen bonds form centrosymmetric dimers. C—H⋯O contacts are also observed. Four C atoms of two benzene rings are disordered over two alternative sites with an occupancy ratio of 0.523 (12):0.427 (12). International Union of Crystallography 2011-11-25 /pmc/articles/PMC3239060/ /pubmed/22199908 http://dx.doi.org/10.1107/S1600536811049178 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Pourayoubi, Mehrdad Shoghpour, Samad Torre-Fernández, Laura García-Granda, Santiago N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenylacetyl)phosphoric triamide |
title |
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenylacetyl)phosphoric triamide |
title_full |
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenylacetyl)phosphoric triamide |
title_fullStr |
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenylacetyl)phosphoric triamide |
title_full_unstemmed |
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenylacetyl)phosphoric triamide |
title_short |
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(2-phenylacetyl)phosphoric triamide |
title_sort | n,n′-dibenzyl-n,n′-dimethyl-n′′-(2-phenylacetyl)phosphoric triamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239060/ https://www.ncbi.nlm.nih.gov/pubmed/22199908 http://dx.doi.org/10.1107/S1600536811049178 |
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