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N (2),N (2),N (6),N (6)-Tetra­kis(2,3,4,5,6-penta­fluoro­benzo­yl)pyridine-2,6-diamine

The title compound, C(33)H(3)F(20)N(3)O(4), is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diamino­pyridine with 2,3,4,5,6-penta­fluoro­benzoyl chloride in a 1:2 molar ratio. The mol­ecule is located on a twofold axis and one of its symmetry...

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Detalles Bibliográficos
Autores principales: Valkonen, Arto, Kolehmainen, Erkki, Ośmiałowski, Borys
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239063/
https://www.ncbi.nlm.nih.gov/pubmed/22199911
http://dx.doi.org/10.1107/S1600536811048768
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author Valkonen, Arto
Kolehmainen, Erkki
Ośmiałowski, Borys
author_facet Valkonen, Arto
Kolehmainen, Erkki
Ośmiałowski, Borys
author_sort Valkonen, Arto
collection PubMed
description The title compound, C(33)H(3)F(20)N(3)O(4), is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diamino­pyridine with 2,3,4,5,6-penta­fluoro­benzoyl chloride in a 1:2 molar ratio. The mol­ecule is located on a twofold axis and one of its symmetry-independent 2,3,4,5,6-penta­fluoro­benzoyl groups is disordered over two sets of sites, the occupancy of the major component being 0.773 (3). In the major component, the dihedral angle between the perfluoro­phenyl groups is 63.64 (10)°, and these groups form dihedral angles of 67.14 (7) and 21.1 (2)° with the pyridine core. Short inter­molecular C—H⋯O and C—H⋯N contacts are found in the crystal structure.
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spelling pubmed-32390632011-12-23 N (2),N (2),N (6),N (6)-Tetra­kis(2,3,4,5,6-penta­fluoro­benzo­yl)pyridine-2,6-diamine Valkonen, Arto Kolehmainen, Erkki Ośmiałowski, Borys Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(33)H(3)F(20)N(3)O(4), is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diamino­pyridine with 2,3,4,5,6-penta­fluoro­benzoyl chloride in a 1:2 molar ratio. The mol­ecule is located on a twofold axis and one of its symmetry-independent 2,3,4,5,6-penta­fluoro­benzoyl groups is disordered over two sets of sites, the occupancy of the major component being 0.773 (3). In the major component, the dihedral angle between the perfluoro­phenyl groups is 63.64 (10)°, and these groups form dihedral angles of 67.14 (7) and 21.1 (2)° with the pyridine core. Short inter­molecular C—H⋯O and C—H⋯N contacts are found in the crystal structure. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3239063/ /pubmed/22199911 http://dx.doi.org/10.1107/S1600536811048768 Text en © Valkonen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Valkonen, Arto
Kolehmainen, Erkki
Ośmiałowski, Borys
N (2),N (2),N (6),N (6)-Tetra­kis(2,3,4,5,6-penta­fluoro­benzo­yl)pyridine-2,6-diamine
title N (2),N (2),N (6),N (6)-Tetra­kis(2,3,4,5,6-penta­fluoro­benzo­yl)pyridine-2,6-diamine
title_full N (2),N (2),N (6),N (6)-Tetra­kis(2,3,4,5,6-penta­fluoro­benzo­yl)pyridine-2,6-diamine
title_fullStr N (2),N (2),N (6),N (6)-Tetra­kis(2,3,4,5,6-penta­fluoro­benzo­yl)pyridine-2,6-diamine
title_full_unstemmed N (2),N (2),N (6),N (6)-Tetra­kis(2,3,4,5,6-penta­fluoro­benzo­yl)pyridine-2,6-diamine
title_short N (2),N (2),N (6),N (6)-Tetra­kis(2,3,4,5,6-penta­fluoro­benzo­yl)pyridine-2,6-diamine
title_sort n (2),n (2),n (6),n (6)-tetra­kis(2,3,4,5,6-penta­fluoro­benzo­yl)pyridine-2,6-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239063/
https://www.ncbi.nlm.nih.gov/pubmed/22199911
http://dx.doi.org/10.1107/S1600536811048768
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