Cargando…
N (2),N (2),N (6),N (6)-Tetrakis(2,3,4,5,6-pentafluorobenzoyl)pyridine-2,6-diamine
The title compound, C(33)H(3)F(20)N(3)O(4), is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diaminopyridine with 2,3,4,5,6-pentafluorobenzoyl chloride in a 1:2 molar ratio. The molecule is located on a twofold axis and one of its symmetry...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239063/ https://www.ncbi.nlm.nih.gov/pubmed/22199911 http://dx.doi.org/10.1107/S1600536811048768 |
_version_ | 1782219116324585472 |
---|---|
author | Valkonen, Arto Kolehmainen, Erkki Ośmiałowski, Borys |
author_facet | Valkonen, Arto Kolehmainen, Erkki Ośmiałowski, Borys |
author_sort | Valkonen, Arto |
collection | PubMed |
description | The title compound, C(33)H(3)F(20)N(3)O(4), is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diaminopyridine with 2,3,4,5,6-pentafluorobenzoyl chloride in a 1:2 molar ratio. The molecule is located on a twofold axis and one of its symmetry-independent 2,3,4,5,6-pentafluorobenzoyl groups is disordered over two sets of sites, the occupancy of the major component being 0.773 (3). In the major component, the dihedral angle between the perfluorophenyl groups is 63.64 (10)°, and these groups form dihedral angles of 67.14 (7) and 21.1 (2)° with the pyridine core. Short intermolecular C—H⋯O and C—H⋯N contacts are found in the crystal structure. |
format | Online Article Text |
id | pubmed-3239063 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32390632011-12-23 N (2),N (2),N (6),N (6)-Tetrakis(2,3,4,5,6-pentafluorobenzoyl)pyridine-2,6-diamine Valkonen, Arto Kolehmainen, Erkki Ośmiałowski, Borys Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(33)H(3)F(20)N(3)O(4), is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diaminopyridine with 2,3,4,5,6-pentafluorobenzoyl chloride in a 1:2 molar ratio. The molecule is located on a twofold axis and one of its symmetry-independent 2,3,4,5,6-pentafluorobenzoyl groups is disordered over two sets of sites, the occupancy of the major component being 0.773 (3). In the major component, the dihedral angle between the perfluorophenyl groups is 63.64 (10)°, and these groups form dihedral angles of 67.14 (7) and 21.1 (2)° with the pyridine core. Short intermolecular C—H⋯O and C—H⋯N contacts are found in the crystal structure. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3239063/ /pubmed/22199911 http://dx.doi.org/10.1107/S1600536811048768 Text en © Valkonen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Valkonen, Arto Kolehmainen, Erkki Ośmiałowski, Borys N (2),N (2),N (6),N (6)-Tetrakis(2,3,4,5,6-pentafluorobenzoyl)pyridine-2,6-diamine |
title |
N
(2),N
(2),N
(6),N
(6)-Tetrakis(2,3,4,5,6-pentafluorobenzoyl)pyridine-2,6-diamine |
title_full |
N
(2),N
(2),N
(6),N
(6)-Tetrakis(2,3,4,5,6-pentafluorobenzoyl)pyridine-2,6-diamine |
title_fullStr |
N
(2),N
(2),N
(6),N
(6)-Tetrakis(2,3,4,5,6-pentafluorobenzoyl)pyridine-2,6-diamine |
title_full_unstemmed |
N
(2),N
(2),N
(6),N
(6)-Tetrakis(2,3,4,5,6-pentafluorobenzoyl)pyridine-2,6-diamine |
title_short |
N
(2),N
(2),N
(6),N
(6)-Tetrakis(2,3,4,5,6-pentafluorobenzoyl)pyridine-2,6-diamine |
title_sort | n
(2),n
(2),n
(6),n
(6)-tetrakis(2,3,4,5,6-pentafluorobenzoyl)pyridine-2,6-diamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239063/ https://www.ncbi.nlm.nih.gov/pubmed/22199911 http://dx.doi.org/10.1107/S1600536811048768 |
work_keys_str_mv | AT valkonenarto n2n2n6n6tetrakis23456pentafluorobenzoylpyridine26diamine AT kolehmainenerkki n2n2n6n6tetrakis23456pentafluorobenzoylpyridine26diamine AT osmiałowskiborys n2n2n6n6tetrakis23456pentafluorobenzoylpyridine26diamine |