5-[(E)-(5-Bromo-2-hy­droxy­benzyl­idene)amino]-1,3,4-thia­diazole-2(3H)-thione

In the title mol­ecule, C(9)H(6)BrN(3)OS(2), the dihedral angle between the benzene ring and the five-membered ring is 5.5 (3)°. An intra­molecular O—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, N—H⋯S hydrogen bonds link mol­ecules into centrosymmetric dimers creating R (2) (2)(8) rin...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239069/
https://www.ncbi.nlm.nih.gov/pubmed/22199917
http://dx.doi.org/10.1107/S1600536811049920
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author Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description In the title mol­ecule, C(9)H(6)BrN(3)OS(2), the dihedral angle between the benzene ring and the five-membered ring is 5.5 (3)°. An intra­molecular O—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, N—H⋯S hydrogen bonds link mol­ecules into centrosymmetric dimers creating R (2) (2)(8) ring motifs. In addition, there are inter­molecular S⋯S [3.430 (2) Å] contacts. The crystal used was a non-merohedral twin with a ratio of 0.113 (3):0.887 (3) for the components.
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spelling pubmed-32390692011-12-23 5-[(E)-(5-Bromo-2-hy­droxy­benzyl­idene)amino]-1,3,4-thia­diazole-2(3H)-thione Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(9)H(6)BrN(3)OS(2), the dihedral angle between the benzene ring and the five-membered ring is 5.5 (3)°. An intra­molecular O—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, N—H⋯S hydrogen bonds link mol­ecules into centrosymmetric dimers creating R (2) (2)(8) ring motifs. In addition, there are inter­molecular S⋯S [3.430 (2) Å] contacts. The crystal used was a non-merohedral twin with a ratio of 0.113 (3):0.887 (3) for the components. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3239069/ /pubmed/22199917 http://dx.doi.org/10.1107/S1600536811049920 Text en © Kargar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
5-[(E)-(5-Bromo-2-hy­droxy­benzyl­idene)amino]-1,3,4-thia­diazole-2(3H)-thione
title 5-[(E)-(5-Bromo-2-hy­droxy­benzyl­idene)amino]-1,3,4-thia­diazole-2(3H)-thione
title_full 5-[(E)-(5-Bromo-2-hy­droxy­benzyl­idene)amino]-1,3,4-thia­diazole-2(3H)-thione
title_fullStr 5-[(E)-(5-Bromo-2-hy­droxy­benzyl­idene)amino]-1,3,4-thia­diazole-2(3H)-thione
title_full_unstemmed 5-[(E)-(5-Bromo-2-hy­droxy­benzyl­idene)amino]-1,3,4-thia­diazole-2(3H)-thione
title_short 5-[(E)-(5-Bromo-2-hy­droxy­benzyl­idene)amino]-1,3,4-thia­diazole-2(3H)-thione
title_sort 5-[(e)-(5-bromo-2-hy­droxy­benzyl­idene)amino]-1,3,4-thia­diazole-2(3h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239069/
https://www.ncbi.nlm.nih.gov/pubmed/22199917
http://dx.doi.org/10.1107/S1600536811049920
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