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Isonicotinamide–2-naphthoic acid (1/1)
In the title 1:1 adduct, C(6)H(6)N(2)O·C(11)H(8)O(2), the amide group is slightly twisted out of the plane of the aromatic ring, with a C—C—C—N torsion angle of 25.11 (19)°, whereas the carboxylic acid group is approximately coplanar with the bicylic ring system, with a C—C—C—O torsion angle of 10...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239073/ https://www.ncbi.nlm.nih.gov/pubmed/22199921 http://dx.doi.org/10.1107/S1600536811050057 |
Sumario: | In the title 1:1 adduct, C(6)H(6)N(2)O·C(11)H(8)O(2), the amide group is slightly twisted out of the plane of the aromatic ring, with a C—C—C—N torsion angle of 25.11 (19)°, whereas the carboxylic acid group is approximately coplanar with the bicylic ring system, with a C—C—C—O torsion angle of 10.9 (2)°. The amide groups from two isonicotinamide molecules form a dimer via N—H⋯O hydrogen bonds. In addition, the 2-naphthanoic acid molecule is hydrogen bonded to the pyridine unit of an isonicotinamide molecule via an O—H⋯N hydrogen bond. This gives rise to a centrosymmetric four-molecule chain, which is cross-linked by further N—H⋯O hydrogen bonds from the amide group. |
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