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{5-Chloro-2-[(2-hydroxybenzylidene)amino]phenyl}(phenyl)methanone
The title Schiff base compound, C(20)H(14)ClNO(2), adopts an E configuration about the azomethine bond. The phenol and chlorobenzene rings form dihedral angles of 84.71 (9) and 80.70 (8)°, respectively, with the phenyl ring and are twisted by 15.32 (8)° with respect to one another. The molecular c...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239075/ https://www.ncbi.nlm.nih.gov/pubmed/22199923 http://dx.doi.org/10.1107/S1600536811048690 |
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author | Aslam, M. Anis, I. Afza, N. Nelofar, A. Yousuf, S. |
author_facet | Aslam, M. Anis, I. Afza, N. Nelofar, A. Yousuf, S. |
author_sort | Aslam, M. |
collection | PubMed |
description | The title Schiff base compound, C(20)H(14)ClNO(2), adopts an E configuration about the azomethine bond. The phenol and chlorobenzene rings form dihedral angles of 84.71 (9) and 80.70 (8)°, respectively, with the phenyl ring and are twisted by 15.32 (8)° with respect to one another. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond, which forms an S(6) ring motif. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming columns parallel to the a axis. |
format | Online Article Text |
id | pubmed-3239075 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32390752011-12-23 {5-Chloro-2-[(2-hydroxybenzylidene)amino]phenyl}(phenyl)methanone Aslam, M. Anis, I. Afza, N. Nelofar, A. Yousuf, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(20)H(14)ClNO(2), adopts an E configuration about the azomethine bond. The phenol and chlorobenzene rings form dihedral angles of 84.71 (9) and 80.70 (8)°, respectively, with the phenyl ring and are twisted by 15.32 (8)° with respect to one another. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond, which forms an S(6) ring motif. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming columns parallel to the a axis. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3239075/ /pubmed/22199923 http://dx.doi.org/10.1107/S1600536811048690 Text en © Aslam et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Aslam, M. Anis, I. Afza, N. Nelofar, A. Yousuf, S. {5-Chloro-2-[(2-hydroxybenzylidene)amino]phenyl}(phenyl)methanone |
title | {5-Chloro-2-[(2-hydroxybenzylidene)amino]phenyl}(phenyl)methanone |
title_full | {5-Chloro-2-[(2-hydroxybenzylidene)amino]phenyl}(phenyl)methanone |
title_fullStr | {5-Chloro-2-[(2-hydroxybenzylidene)amino]phenyl}(phenyl)methanone |
title_full_unstemmed | {5-Chloro-2-[(2-hydroxybenzylidene)amino]phenyl}(phenyl)methanone |
title_short | {5-Chloro-2-[(2-hydroxybenzylidene)amino]phenyl}(phenyl)methanone |
title_sort | {5-chloro-2-[(2-hydroxybenzylidene)amino]phenyl}(phenyl)methanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239075/ https://www.ncbi.nlm.nih.gov/pubmed/22199923 http://dx.doi.org/10.1107/S1600536811048690 |
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