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{5-Chloro-2-[(2-hy­droxy­benzyl­idene)amino]­phen­yl}(phen­yl)methanone

The title Schiff base compound, C(20)H(14)ClNO(2), adopts an E configuration about the azomethine bond. The phenol and chloro­benzene rings form dihedral angles of 84.71 (9) and 80.70 (8)°, respectively, with the phenyl ring and are twisted by 15.32 (8)° with respect to one another. The mol­ecular c...

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Detalles Bibliográficos
Autores principales: Aslam, M., Anis, I., Afza, N., Nelofar, A., Yousuf, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239075/
https://www.ncbi.nlm.nih.gov/pubmed/22199923
http://dx.doi.org/10.1107/S1600536811048690
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author Aslam, M.
Anis, I.
Afza, N.
Nelofar, A.
Yousuf, S.
author_facet Aslam, M.
Anis, I.
Afza, N.
Nelofar, A.
Yousuf, S.
author_sort Aslam, M.
collection PubMed
description The title Schiff base compound, C(20)H(14)ClNO(2), adopts an E configuration about the azomethine bond. The phenol and chloro­benzene rings form dihedral angles of 84.71 (9) and 80.70 (8)°, respectively, with the phenyl ring and are twisted by 15.32 (8)° with respect to one another. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, which forms an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming columns parallel to the a axis.
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spelling pubmed-32390752011-12-23 {5-Chloro-2-[(2-hy­droxy­benzyl­idene)amino]­phen­yl}(phen­yl)methanone Aslam, M. Anis, I. Afza, N. Nelofar, A. Yousuf, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(20)H(14)ClNO(2), adopts an E configuration about the azomethine bond. The phenol and chloro­benzene rings form dihedral angles of 84.71 (9) and 80.70 (8)°, respectively, with the phenyl ring and are twisted by 15.32 (8)° with respect to one another. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, which forms an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming columns parallel to the a axis. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3239075/ /pubmed/22199923 http://dx.doi.org/10.1107/S1600536811048690 Text en © Aslam et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Aslam, M.
Anis, I.
Afza, N.
Nelofar, A.
Yousuf, S.
{5-Chloro-2-[(2-hy­droxy­benzyl­idene)amino]­phen­yl}(phen­yl)methanone
title {5-Chloro-2-[(2-hy­droxy­benzyl­idene)amino]­phen­yl}(phen­yl)methanone
title_full {5-Chloro-2-[(2-hy­droxy­benzyl­idene)amino]­phen­yl}(phen­yl)methanone
title_fullStr {5-Chloro-2-[(2-hy­droxy­benzyl­idene)amino]­phen­yl}(phen­yl)methanone
title_full_unstemmed {5-Chloro-2-[(2-hy­droxy­benzyl­idene)amino]­phen­yl}(phen­yl)methanone
title_short {5-Chloro-2-[(2-hy­droxy­benzyl­idene)amino]­phen­yl}(phen­yl)methanone
title_sort {5-chloro-2-[(2-hy­droxy­benzyl­idene)amino]­phen­yl}(phen­yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239075/
https://www.ncbi.nlm.nih.gov/pubmed/22199923
http://dx.doi.org/10.1107/S1600536811048690
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AT afzan 5chloro22hydroxybenzylideneaminophenylphenylmethanone
AT nelofara 5chloro22hydroxybenzylideneaminophenylphenylmethanone
AT yousufs 5chloro22hydroxybenzylideneaminophenylphenylmethanone