1,3-Bis(2-cyano­benz­yl)imidazolium bromide

In the title salt, C(19)H(15)N(4) (+)·Br(−), the central imidazole ring makes dihedral angles of 83.1 (2) and 87.6 (2)° with the terminal benzene rings. The dihedral angle between the terminal benzene rings is 6.77 (19)°; the cyanide substituents have an anti orientation. In the crystal, the cations...

Descripción completa

Detalles Bibliográficos
Autores principales: Haque, Rosenani A., Ahmed, Safaa A., Zetty, Zulikha H., Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239090/
https://www.ncbi.nlm.nih.gov/pubmed/22199938
http://dx.doi.org/10.1107/S1600536811048951
_version_ 1782219122429394944
author Haque, Rosenani A.
Ahmed, Safaa A.
Zetty, Zulikha H.
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Haque, Rosenani A.
Ahmed, Safaa A.
Zetty, Zulikha H.
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Haque, Rosenani A.
collection PubMed
description In the title salt, C(19)H(15)N(4) (+)·Br(−), the central imidazole ring makes dihedral angles of 83.1 (2) and 87.6 (2)° with the terminal benzene rings. The dihedral angle between the terminal benzene rings is 6.77 (19)°; the cyanide substituents have an anti orientation. In the crystal, the cations and anions are linked via C—H⋯N and C—H⋯Br hydrogen bonds, forming sheets lying parallel to the ac plane.
format Online
Article
Text
id pubmed-3239090
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32390902011-12-23 1,3-Bis(2-cyano­benz­yl)imidazolium bromide Haque, Rosenani A. Ahmed, Safaa A. Zetty, Zulikha H. Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(19)H(15)N(4) (+)·Br(−), the central imidazole ring makes dihedral angles of 83.1 (2) and 87.6 (2)° with the terminal benzene rings. The dihedral angle between the terminal benzene rings is 6.77 (19)°; the cyanide substituents have an anti orientation. In the crystal, the cations and anions are linked via C—H⋯N and C—H⋯Br hydrogen bonds, forming sheets lying parallel to the ac plane. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239090/ /pubmed/22199938 http://dx.doi.org/10.1107/S1600536811048951 Text en © Haque et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Haque, Rosenani A.
Ahmed, Safaa A.
Zetty, Zulikha H.
Hemamalini, Madhukar
Fun, Hoong-Kun
1,3-Bis(2-cyano­benz­yl)imidazolium bromide
title 1,3-Bis(2-cyano­benz­yl)imidazolium bromide
title_full 1,3-Bis(2-cyano­benz­yl)imidazolium bromide
title_fullStr 1,3-Bis(2-cyano­benz­yl)imidazolium bromide
title_full_unstemmed 1,3-Bis(2-cyano­benz­yl)imidazolium bromide
title_short 1,3-Bis(2-cyano­benz­yl)imidazolium bromide
title_sort 1,3-bis(2-cyano­benz­yl)imidazolium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239090/
https://www.ncbi.nlm.nih.gov/pubmed/22199938
http://dx.doi.org/10.1107/S1600536811048951
work_keys_str_mv AT haquerosenania 13bis2cyanobenzylimidazoliumbromide
AT ahmedsafaaa 13bis2cyanobenzylimidazoliumbromide
AT zettyzulikhah 13bis2cyanobenzylimidazoliumbromide
AT hemamalinimadhukar 13bis2cyanobenzylimidazoliumbromide
AT funhoongkun 13bis2cyanobenzylimidazoliumbromide

Ejemplares similares