N,N′,N′′-Tricyclo­hexyl­guanidinium iodide

In the title compound, C(19)H(36)N(3) (+)·I(−), the orientation of the cyclo­hexyl rings around the planar (sum of N—C—N angles = 360°) CN(3) (+) unit produces steric hindrance around the N—H groups. As a consequence of this particular orientation of the tricyclo­hexyl­guanidinium cation (hereafter...

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Detalles Bibliográficos
Autores principales: Said, Farouq F., Ali, Basem F., Richeson, Darrin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239094/
https://www.ncbi.nlm.nih.gov/pubmed/22199942
http://dx.doi.org/10.1107/S1600536811049683
Descripción
Sumario:In the title compound, C(19)H(36)N(3) (+)·I(−), the orientation of the cyclo­hexyl rings around the planar (sum of N—C—N angles = 360°) CN(3) (+) unit produces steric hindrance around the N—H groups. As a consequence of this particular orientation of the tricyclo­hexyl­guanidinium cation (hereafter denoted CHGH(+)), hydrogen bonding is restricted to classical N—H⋯I and non-clasical (cyclo­hex­yl)C—H⋯I hydrogen bonds. The propeller CHGH(+) cation and the oriented hydrogen-bonding interactions lead to a three-dimensional supra­molecular structure.

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