N,N′,N′′-Tricyclo­hexyl­guanidinium iodide

In the title compound, C(19)H(36)N(3) (+)·I(−), the orientation of the cyclo­hexyl rings around the planar (sum of N—C—N angles = 360°) CN(3) (+) unit produces steric hindrance around the N—H groups. As a consequence of this particular orientation of the tricyclo­hexyl­guanidinium cation (hereafter...

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Detalles Bibliográficos
Autores principales: Said, Farouq F., Ali, Basem F., Richeson, Darrin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239094/
https://www.ncbi.nlm.nih.gov/pubmed/22199942
http://dx.doi.org/10.1107/S1600536811049683
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author Said, Farouq F.
Ali, Basem F.
Richeson, Darrin
author_facet Said, Farouq F.
Ali, Basem F.
Richeson, Darrin
author_sort Said, Farouq F.
collection PubMed
description In the title compound, C(19)H(36)N(3) (+)·I(−), the orientation of the cyclo­hexyl rings around the planar (sum of N—C—N angles = 360°) CN(3) (+) unit produces steric hindrance around the N—H groups. As a consequence of this particular orientation of the tricyclo­hexyl­guanidinium cation (hereafter denoted CHGH(+)), hydrogen bonding is restricted to classical N—H⋯I and non-clasical (cyclo­hex­yl)C—H⋯I hydrogen bonds. The propeller CHGH(+) cation and the oriented hydrogen-bonding interactions lead to a three-dimensional supra­molecular structure.
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spelling pubmed-32390942011-12-23 N,N′,N′′-Tricyclo­hexyl­guanidinium iodide Said, Farouq F. Ali, Basem F. Richeson, Darrin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(36)N(3) (+)·I(−), the orientation of the cyclo­hexyl rings around the planar (sum of N—C—N angles = 360°) CN(3) (+) unit produces steric hindrance around the N—H groups. As a consequence of this particular orientation of the tricyclo­hexyl­guanidinium cation (hereafter denoted CHGH(+)), hydrogen bonding is restricted to classical N—H⋯I and non-clasical (cyclo­hex­yl)C—H⋯I hydrogen bonds. The propeller CHGH(+) cation and the oriented hydrogen-bonding interactions lead to a three-dimensional supra­molecular structure. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239094/ /pubmed/22199942 http://dx.doi.org/10.1107/S1600536811049683 Text en © Said et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Said, Farouq F.
Ali, Basem F.
Richeson, Darrin
N,N′,N′′-Tricyclo­hexyl­guanidinium iodide
title N,N′,N′′-Tricyclo­hexyl­guanidinium iodide
title_full N,N′,N′′-Tricyclo­hexyl­guanidinium iodide
title_fullStr N,N′,N′′-Tricyclo­hexyl­guanidinium iodide
title_full_unstemmed N,N′,N′′-Tricyclo­hexyl­guanidinium iodide
title_short N,N′,N′′-Tricyclo­hexyl­guanidinium iodide
title_sort n,n′,n′′-tricyclo­hexyl­guanidinium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239094/
https://www.ncbi.nlm.nih.gov/pubmed/22199942
http://dx.doi.org/10.1107/S1600536811049683
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