(Z)-2-(5-Methyl-2-oxoindolin-3-yl­idene)-N-phenyl­hydrazinecarbothio­amide

In the title compound, C(16)H(14)N(4)OS, the dihedral angle between the nine-membered 5-methyl­indolin-2-one ring system and the benzene ring is 10.21 (7)°. Intra­molecular cyclic N—H⋯O and C—H⋯S hydrogen-bonding inter­actions [graph set S(6)] are present within the N—N—C—N chain between the ring sy...

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Autores principales: Qasem Ali, Amna, Eltayeb, Naser Eltaher, Teoh, Siang Guan, Salhin, Abdussalam, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239102/
https://www.ncbi.nlm.nih.gov/pubmed/22199950
http://dx.doi.org/10.1107/S1600536811049154
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author Qasem Ali, Amna
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Salhin, Abdussalam
Fun, Hoong-Kun
author_facet Qasem Ali, Amna
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Salhin, Abdussalam
Fun, Hoong-Kun
author_sort Qasem Ali, Amna
collection PubMed
description In the title compound, C(16)H(14)N(4)OS, the dihedral angle between the nine-membered 5-methyl­indolin-2-one ring system and the benzene ring is 10.21 (7)°. Intra­molecular cyclic N—H⋯O and C—H⋯S hydrogen-bonding inter­actions [graph set S(6)] are present within the N—N—C—N chain between the ring systems. In the crystal, mol­ecules form centrosymmetric cyclic dimers through pairs of N—H⋯O hydrogen bonds [graph set R (2) (2)(8)].
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spelling pubmed-32391022011-12-23 (Z)-2-(5-Methyl-2-oxoindolin-3-yl­idene)-N-phenyl­hydrazinecarbothio­amide Qasem Ali, Amna Eltayeb, Naser Eltaher Teoh, Siang Guan Salhin, Abdussalam Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(14)N(4)OS, the dihedral angle between the nine-membered 5-methyl­indolin-2-one ring system and the benzene ring is 10.21 (7)°. Intra­molecular cyclic N—H⋯O and C—H⋯S hydrogen-bonding inter­actions [graph set S(6)] are present within the N—N—C—N chain between the ring systems. In the crystal, mol­ecules form centrosymmetric cyclic dimers through pairs of N—H⋯O hydrogen bonds [graph set R (2) (2)(8)]. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239102/ /pubmed/22199950 http://dx.doi.org/10.1107/S1600536811049154 Text en © Qasem Ali et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Qasem Ali, Amna
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Salhin, Abdussalam
Fun, Hoong-Kun
(Z)-2-(5-Methyl-2-oxoindolin-3-yl­idene)-N-phenyl­hydrazinecarbothio­amide
title (Z)-2-(5-Methyl-2-oxoindolin-3-yl­idene)-N-phenyl­hydrazinecarbothio­amide
title_full (Z)-2-(5-Methyl-2-oxoindolin-3-yl­idene)-N-phenyl­hydrazinecarbothio­amide
title_fullStr (Z)-2-(5-Methyl-2-oxoindolin-3-yl­idene)-N-phenyl­hydrazinecarbothio­amide
title_full_unstemmed (Z)-2-(5-Methyl-2-oxoindolin-3-yl­idene)-N-phenyl­hydrazinecarbothio­amide
title_short (Z)-2-(5-Methyl-2-oxoindolin-3-yl­idene)-N-phenyl­hydrazinecarbothio­amide
title_sort (z)-2-(5-methyl-2-oxoindolin-3-yl­idene)-n-phenyl­hydrazinecarbothio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239102/
https://www.ncbi.nlm.nih.gov/pubmed/22199950
http://dx.doi.org/10.1107/S1600536811049154
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