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1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)­oxy]butane

The title compound, C(34)H(28)N(6)O(2), has an inversion centre located at the mid-point of the central C—C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the brid...

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Detalles Bibliográficos
Autores principales: Akerman, Matthew P., Grimmer, Craig D., Nikolayenko, Varvara I., Reddy, Desigan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239103/
https://www.ncbi.nlm.nih.gov/pubmed/22199951
http://dx.doi.org/10.1107/S1600536811050343
Descripción
Sumario:The title compound, C(34)H(28)N(6)O(2), has an inversion centre located at the mid-point of the central C—C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the bridging unit and the central pyridyl ring is for the pyridyl N atom which sits 0.055 (1) Å above the plane. The dihedral angles between the terminal pyridine rings with this plane are 10.3 (1) and 37.6 (1)°, repectively. In the crystal, weak C—H⋯N inter­actions link the mol­ecules into infinite chains parallel to the a axis.