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1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)oxy]butane
The title compound, C(34)H(28)N(6)O(2), has an inversion centre located at the mid-point of the central C—C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the brid...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239103/ https://www.ncbi.nlm.nih.gov/pubmed/22199951 http://dx.doi.org/10.1107/S1600536811050343 |
Sumario: | The title compound, C(34)H(28)N(6)O(2), has an inversion centre located at the mid-point of the central C—C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the bridging unit and the central pyridyl ring is for the pyridyl N atom which sits 0.055 (1) Å above the plane. The dihedral angles between the terminal pyridine rings with this plane are 10.3 (1) and 37.6 (1)°, repectively. In the crystal, weak C—H⋯N interactions link the molecules into infinite chains parallel to the a axis. |
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