1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)­oxy]butane

The title compound, C(34)H(28)N(6)O(2), has an inversion centre located at the mid-point of the central C—C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the brid...

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Autores principales: Akerman, Matthew P., Grimmer, Craig D., Nikolayenko, Varvara I., Reddy, Desigan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239103/
https://www.ncbi.nlm.nih.gov/pubmed/22199951
http://dx.doi.org/10.1107/S1600536811050343
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author Akerman, Matthew P.
Grimmer, Craig D.
Nikolayenko, Varvara I.
Reddy, Desigan
author_facet Akerman, Matthew P.
Grimmer, Craig D.
Nikolayenko, Varvara I.
Reddy, Desigan
author_sort Akerman, Matthew P.
collection PubMed
description The title compound, C(34)H(28)N(6)O(2), has an inversion centre located at the mid-point of the central C—C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the bridging unit and the central pyridyl ring is for the pyridyl N atom which sits 0.055 (1) Å above the plane. The dihedral angles between the terminal pyridine rings with this plane are 10.3 (1) and 37.6 (1)°, repectively. In the crystal, weak C—H⋯N inter­actions link the mol­ecules into infinite chains parallel to the a axis.
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spelling pubmed-32391032011-12-23 1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)­oxy]butane Akerman, Matthew P. Grimmer, Craig D. Nikolayenko, Varvara I. Reddy, Desigan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(34)H(28)N(6)O(2), has an inversion centre located at the mid-point of the central C—C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the bridging unit and the central pyridyl ring is for the pyridyl N atom which sits 0.055 (1) Å above the plane. The dihedral angles between the terminal pyridine rings with this plane are 10.3 (1) and 37.6 (1)°, repectively. In the crystal, weak C—H⋯N inter­actions link the mol­ecules into infinite chains parallel to the a axis. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239103/ /pubmed/22199951 http://dx.doi.org/10.1107/S1600536811050343 Text en © Akerman et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akerman, Matthew P.
Grimmer, Craig D.
Nikolayenko, Varvara I.
Reddy, Desigan
1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)­oxy]butane
title 1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)­oxy]butane
title_full 1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)­oxy]butane
title_fullStr 1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)­oxy]butane
title_full_unstemmed 1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)­oxy]butane
title_short 1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)­oxy]butane
title_sort 1,4-bis[(2,2′:6′,2′′-terpyridin-4′-yl)­oxy]butane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239103/
https://www.ncbi.nlm.nih.gov/pubmed/22199951
http://dx.doi.org/10.1107/S1600536811050343
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AT reddydesigan 14bis2262terpyridin4yloxybutane

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