5-Methyl-12-phenyl­sulfonyl-12H-naphtho­[1,2-b]carbazole

In the title compound, C(27)H(19)NO(2)S, the naphtho­carbazole unit is approximately planar (r.m.s. deviation = 0.002 Å) except for the N atom, which is displaced by 0.122 (1) Å out of the mean plane. The dihedral angle between the naphtho­carbazole mean plane and the phenyl ring of the phenyl­sulfo...

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Detalles Bibliográficos
Autores principales: Vasudhevan, S., Karunakaran, R. Joel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239104/
https://www.ncbi.nlm.nih.gov/pubmed/22199952
http://dx.doi.org/10.1107/S160053681104949X
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author Vasudhevan, S.
Karunakaran, R. Joel
author_facet Vasudhevan, S.
Karunakaran, R. Joel
author_sort Vasudhevan, S.
collection PubMed
description In the title compound, C(27)H(19)NO(2)S, the naphtho­carbazole unit is approximately planar (r.m.s. deviation = 0.002 Å) except for the N atom, which is displaced by 0.122 (1) Å out of the mean plane. The dihedral angle between the naphtho­carbazole mean plane and the phenyl ring of the phenyl­sulfonyl substituent is 83.16 (3)°. An inter­molecular C—H⋯π inter­action involving the phenyl group and the pyrrole ring is observed in the crystal structure.
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spelling pubmed-32391042011-12-23 5-Methyl-12-phenyl­sulfonyl-12H-naphtho­[1,2-b]carbazole Vasudhevan, S. Karunakaran, R. Joel Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(19)NO(2)S, the naphtho­carbazole unit is approximately planar (r.m.s. deviation = 0.002 Å) except for the N atom, which is displaced by 0.122 (1) Å out of the mean plane. The dihedral angle between the naphtho­carbazole mean plane and the phenyl ring of the phenyl­sulfonyl substituent is 83.16 (3)°. An inter­molecular C—H⋯π inter­action involving the phenyl group and the pyrrole ring is observed in the crystal structure. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239104/ /pubmed/22199952 http://dx.doi.org/10.1107/S160053681104949X Text en © Vasudhevan and Karunakaran 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vasudhevan, S.
Karunakaran, R. Joel
5-Methyl-12-phenyl­sulfonyl-12H-naphtho­[1,2-b]carbazole
title 5-Methyl-12-phenyl­sulfonyl-12H-naphtho­[1,2-b]carbazole
title_full 5-Methyl-12-phenyl­sulfonyl-12H-naphtho­[1,2-b]carbazole
title_fullStr 5-Methyl-12-phenyl­sulfonyl-12H-naphtho­[1,2-b]carbazole
title_full_unstemmed 5-Methyl-12-phenyl­sulfonyl-12H-naphtho­[1,2-b]carbazole
title_short 5-Methyl-12-phenyl­sulfonyl-12H-naphtho­[1,2-b]carbazole
title_sort 5-methyl-12-phenyl­sulfonyl-12h-naphtho­[1,2-b]carbazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239104/
https://www.ncbi.nlm.nih.gov/pubmed/22199952
http://dx.doi.org/10.1107/S160053681104949X
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