Benzyl 5-phenyl­pyrazolo­[5,1-a]isoquino­line-1-carboxyl­ate

In the title compound, C(25)H(18)N(2)O(2), the pyrazolo­[5,1-a]iso­quin­oline ring system is approximately planar [maximum deviation = 0.027 (2) Å] and is oriented at dihedral angles of 57.22 (6) and 71.36 (7)° with respect to the two phenyl rings. The phenyl rings are twisted to each other by a dih...

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Autores principales: Lu, Yu-Kun, Yao, Xiao, Luo, Li-Wen, Lü, Ren-Qing, Liu, Yun-Qi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239112/
https://www.ncbi.nlm.nih.gov/pubmed/22199960
http://dx.doi.org/10.1107/S1600536811050586
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author Lu, Yu-Kun
Yao, Xiao
Luo, Li-Wen
Lü, Ren-Qing
Liu, Yun-Qi
author_facet Lu, Yu-Kun
Yao, Xiao
Luo, Li-Wen
Lü, Ren-Qing
Liu, Yun-Qi
author_sort Lu, Yu-Kun
collection PubMed
description In the title compound, C(25)H(18)N(2)O(2), the pyrazolo­[5,1-a]iso­quin­oline ring system is approximately planar [maximum deviation = 0.027 (2) Å] and is oriented at dihedral angles of 57.22 (6) and 71.36 (7)° with respect to the two phenyl rings. The phenyl rings are twisted to each other by a dihedral angle of 66.33 (8)°. A weak intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, weak C—H⋯π inter­actions are present.
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spelling pubmed-32391122011-12-23 Benzyl 5-phenyl­pyrazolo­[5,1-a]isoquino­line-1-carboxyl­ate Lu, Yu-Kun Yao, Xiao Luo, Li-Wen Lü, Ren-Qing Liu, Yun-Qi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(18)N(2)O(2), the pyrazolo­[5,1-a]iso­quin­oline ring system is approximately planar [maximum deviation = 0.027 (2) Å] and is oriented at dihedral angles of 57.22 (6) and 71.36 (7)° with respect to the two phenyl rings. The phenyl rings are twisted to each other by a dihedral angle of 66.33 (8)°. A weak intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, weak C—H⋯π inter­actions are present. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239112/ /pubmed/22199960 http://dx.doi.org/10.1107/S1600536811050586 Text en © Lu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lu, Yu-Kun
Yao, Xiao
Luo, Li-Wen
Lü, Ren-Qing
Liu, Yun-Qi
Benzyl 5-phenyl­pyrazolo­[5,1-a]isoquino­line-1-carboxyl­ate
title Benzyl 5-phenyl­pyrazolo­[5,1-a]isoquino­line-1-carboxyl­ate
title_full Benzyl 5-phenyl­pyrazolo­[5,1-a]isoquino­line-1-carboxyl­ate
title_fullStr Benzyl 5-phenyl­pyrazolo­[5,1-a]isoquino­line-1-carboxyl­ate
title_full_unstemmed Benzyl 5-phenyl­pyrazolo­[5,1-a]isoquino­line-1-carboxyl­ate
title_short Benzyl 5-phenyl­pyrazolo­[5,1-a]isoquino­line-1-carboxyl­ate
title_sort benzyl 5-phenyl­pyrazolo­[5,1-a]isoquino­line-1-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239112/
https://www.ncbi.nlm.nih.gov/pubmed/22199960
http://dx.doi.org/10.1107/S1600536811050586
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