(5RS,10SR,15RS)-Trimethyl­truxene

The title mol­ecule, C(30)H(24), was prepared as a possible precursor to buckminsterfullerene cages. The two enanti­omers adopt the anti configuration, with one S/R and two R/S methyl groups, one anti to the other two. The truxene framework is slightly non-planar: with respect to the central six-rin...

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Detalles Bibliográficos
Autores principales: Thomas, Kandace R., Dhar, Raj K., Fronczek, Frank R., Watkins, Steven F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239118/
https://www.ncbi.nlm.nih.gov/pubmed/22199966
http://dx.doi.org/10.1107/S1600536811048616
Descripción
Sumario:The title mol­ecule, C(30)H(24), was prepared as a possible precursor to buckminsterfullerene cages. The two enanti­omers adopt the anti configuration, with one S/R and two R/S methyl groups, one anti to the other two. The truxene framework is slightly non-planar: with respect to the central six-ring mean plane, the three methyl C atoms are 1.377 (3), −1.475 (3) and 1.515 (3) Å distant, whereas the respective proximate peripheral six-ring mean planes make dihedral angles of 6.27 (6), 3.45 (7) and −7.37 (7)°.

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