(5RS,10SR,15RS)-Trimethyl­truxene

The title mol­ecule, C(30)H(24), was prepared as a possible precursor to buckminsterfullerene cages. The two enanti­omers adopt the anti configuration, with one S/R and two R/S methyl groups, one anti to the other two. The truxene framework is slightly non-planar: with respect to the central six-rin...

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Detalles Bibliográficos
Autores principales: Thomas, Kandace R., Dhar, Raj K., Fronczek, Frank R., Watkins, Steven F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239118/
https://www.ncbi.nlm.nih.gov/pubmed/22199966
http://dx.doi.org/10.1107/S1600536811048616
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author Thomas, Kandace R.
Dhar, Raj K.
Fronczek, Frank R.
Watkins, Steven F.
author_facet Thomas, Kandace R.
Dhar, Raj K.
Fronczek, Frank R.
Watkins, Steven F.
author_sort Thomas, Kandace R.
collection PubMed
description The title mol­ecule, C(30)H(24), was prepared as a possible precursor to buckminsterfullerene cages. The two enanti­omers adopt the anti configuration, with one S/R and two R/S methyl groups, one anti to the other two. The truxene framework is slightly non-planar: with respect to the central six-ring mean plane, the three methyl C atoms are 1.377 (3), −1.475 (3) and 1.515 (3) Å distant, whereas the respective proximate peripheral six-ring mean planes make dihedral angles of 6.27 (6), 3.45 (7) and −7.37 (7)°.
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spelling pubmed-32391182011-12-23 (5RS,10SR,15RS)-Trimethyl­truxene Thomas, Kandace R. Dhar, Raj K. Fronczek, Frank R. Watkins, Steven F. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(30)H(24), was prepared as a possible precursor to buckminsterfullerene cages. The two enanti­omers adopt the anti configuration, with one S/R and two R/S methyl groups, one anti to the other two. The truxene framework is slightly non-planar: with respect to the central six-ring mean plane, the three methyl C atoms are 1.377 (3), −1.475 (3) and 1.515 (3) Å distant, whereas the respective proximate peripheral six-ring mean planes make dihedral angles of 6.27 (6), 3.45 (7) and −7.37 (7)°. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239118/ /pubmed/22199966 http://dx.doi.org/10.1107/S1600536811048616 Text en © Thomas et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thomas, Kandace R.
Dhar, Raj K.
Fronczek, Frank R.
Watkins, Steven F.
(5RS,10SR,15RS)-Trimethyl­truxene
title (5RS,10SR,15RS)-Trimethyl­truxene
title_full (5RS,10SR,15RS)-Trimethyl­truxene
title_fullStr (5RS,10SR,15RS)-Trimethyl­truxene
title_full_unstemmed (5RS,10SR,15RS)-Trimethyl­truxene
title_short (5RS,10SR,15RS)-Trimethyl­truxene
title_sort (5rs,10sr,15rs)-trimethyl­truxene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239118/
https://www.ncbi.nlm.nih.gov/pubmed/22199966
http://dx.doi.org/10.1107/S1600536811048616
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AT watkinsstevenf 5rs10sr15rstrimethyltruxene

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