(2R,3R)-1-(4-Chloro­phen­yl)-2-[(S)-2-nitro-1-phenyl­eth­yl]-3-phenyl­pentan-1-one

The title compound, C(25)H(24)ClNO(3), has three contiguous chiral centres. The absolute structure was determined by anomalous dispersion. The chloro­benzene ring is inclined to the two phenyl rings by 14.98 (9) and 59.05 (9)°. The two phenyl rings are inclined to one another by 49.51 (10)°. In the...

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Detalles Bibliográficos
Autores principales: Duo, De-Long, Ni, Cheng-Yan, Wen, Qing-Song
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239119/
https://www.ncbi.nlm.nih.gov/pubmed/22199967
http://dx.doi.org/10.1107/S1600536811050306
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author Duo, De-Long
Ni, Cheng-Yan
Wen, Qing-Song
author_facet Duo, De-Long
Ni, Cheng-Yan
Wen, Qing-Song
author_sort Duo, De-Long
collection PubMed
description The title compound, C(25)H(24)ClNO(3), has three contiguous chiral centres. The absolute structure was determined by anomalous dispersion. The chloro­benzene ring is inclined to the two phenyl rings by 14.98 (9) and 59.05 (9)°. The two phenyl rings are inclined to one another by 49.51 (10)°. In the crystal, neighbouring mol­ecules are linked via C—H⋯O hydrogen bonds, forming chains propagating along [010]. There is also a C—H⋯π inter­action present that leads to the formation of a three-dimensional network.
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spelling pubmed-32391192011-12-23 (2R,3R)-1-(4-Chloro­phen­yl)-2-[(S)-2-nitro-1-phenyl­eth­yl]-3-phenyl­pentan-1-one Duo, De-Long Ni, Cheng-Yan Wen, Qing-Song Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(24)ClNO(3), has three contiguous chiral centres. The absolute structure was determined by anomalous dispersion. The chloro­benzene ring is inclined to the two phenyl rings by 14.98 (9) and 59.05 (9)°. The two phenyl rings are inclined to one another by 49.51 (10)°. In the crystal, neighbouring mol­ecules are linked via C—H⋯O hydrogen bonds, forming chains propagating along [010]. There is also a C—H⋯π inter­action present that leads to the formation of a three-dimensional network. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239119/ /pubmed/22199967 http://dx.doi.org/10.1107/S1600536811050306 Text en © Duo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Duo, De-Long
Ni, Cheng-Yan
Wen, Qing-Song
(2R,3R)-1-(4-Chloro­phen­yl)-2-[(S)-2-nitro-1-phenyl­eth­yl]-3-phenyl­pentan-1-one
title (2R,3R)-1-(4-Chloro­phen­yl)-2-[(S)-2-nitro-1-phenyl­eth­yl]-3-phenyl­pentan-1-one
title_full (2R,3R)-1-(4-Chloro­phen­yl)-2-[(S)-2-nitro-1-phenyl­eth­yl]-3-phenyl­pentan-1-one
title_fullStr (2R,3R)-1-(4-Chloro­phen­yl)-2-[(S)-2-nitro-1-phenyl­eth­yl]-3-phenyl­pentan-1-one
title_full_unstemmed (2R,3R)-1-(4-Chloro­phen­yl)-2-[(S)-2-nitro-1-phenyl­eth­yl]-3-phenyl­pentan-1-one
title_short (2R,3R)-1-(4-Chloro­phen­yl)-2-[(S)-2-nitro-1-phenyl­eth­yl]-3-phenyl­pentan-1-one
title_sort (2r,3r)-1-(4-chloro­phen­yl)-2-[(s)-2-nitro-1-phenyl­eth­yl]-3-phenyl­pentan-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239119/
https://www.ncbi.nlm.nih.gov/pubmed/22199967
http://dx.doi.org/10.1107/S1600536811050306
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