Cargando…
(E)-1-[1-(2-Chlorophenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine
The title molecule, C(14)H(11)ClN(4)O(4), is in an E configuration and is twisted with the dihedral angle between the two benzene rings being 38.48 (8)°. The ethylidenehydrazine plane makes dihedral angles of 6.03 (10) and 44.04 (11)°, respectively, with the dinitro- and chloro-substituted benzene...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239123/ https://www.ncbi.nlm.nih.gov/pubmed/22199971 http://dx.doi.org/10.1107/S160053681105001X |
_version_ | 1782219129941393408 |
---|---|
author | Chantrapromma, Suchada Nilwanna, Boonlerd Jansrisewangwong, Patcharaporn Kobkeatthawin, Thawanrat Fun, Hoong-Kun |
author_facet | Chantrapromma, Suchada Nilwanna, Boonlerd Jansrisewangwong, Patcharaporn Kobkeatthawin, Thawanrat Fun, Hoong-Kun |
author_sort | Chantrapromma, Suchada |
collection | PubMed |
description | The title molecule, C(14)H(11)ClN(4)O(4), is in an E configuration and is twisted with the dihedral angle between the two benzene rings being 38.48 (8)°. The ethylidenehydrazine plane makes dihedral angles of 6.03 (10) and 44.04 (11)°, respectively, with the dinitro- and chloro-substituted benzene rings. The two nitro groups are essentially coplanar with the bound benzene ring, making dihedral angles of 0.9 (2) and 1.65 (18)°. An intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by a weak C—H⋯O interaction into a chain along the c axis. The chains are further stacked along the b axis by a π–π interaction with a centroid–centroid distance of 3.6088 (10) Å. |
format | Online Article Text |
id | pubmed-3239123 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32391232011-12-23 (E)-1-[1-(2-Chlorophenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine Chantrapromma, Suchada Nilwanna, Boonlerd Jansrisewangwong, Patcharaporn Kobkeatthawin, Thawanrat Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(14)H(11)ClN(4)O(4), is in an E configuration and is twisted with the dihedral angle between the two benzene rings being 38.48 (8)°. The ethylidenehydrazine plane makes dihedral angles of 6.03 (10) and 44.04 (11)°, respectively, with the dinitro- and chloro-substituted benzene rings. The two nitro groups are essentially coplanar with the bound benzene ring, making dihedral angles of 0.9 (2) and 1.65 (18)°. An intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by a weak C—H⋯O interaction into a chain along the c axis. The chains are further stacked along the b axis by a π–π interaction with a centroid–centroid distance of 3.6088 (10) Å. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239123/ /pubmed/22199971 http://dx.doi.org/10.1107/S160053681105001X Text en © Chantrapromma et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chantrapromma, Suchada Nilwanna, Boonlerd Jansrisewangwong, Patcharaporn Kobkeatthawin, Thawanrat Fun, Hoong-Kun (E)-1-[1-(2-Chlorophenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine |
title | (E)-1-[1-(2-Chlorophenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine |
title_full | (E)-1-[1-(2-Chlorophenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine |
title_fullStr | (E)-1-[1-(2-Chlorophenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine |
title_full_unstemmed | (E)-1-[1-(2-Chlorophenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine |
title_short | (E)-1-[1-(2-Chlorophenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine |
title_sort | (e)-1-[1-(2-chlorophenyl)ethylidene]-2-(2,4-dinitrophenyl)hydrazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239123/ https://www.ncbi.nlm.nih.gov/pubmed/22199971 http://dx.doi.org/10.1107/S160053681105001X |
work_keys_str_mv | AT chantraprommasuchada e112chlorophenylethylidene224dinitrophenylhydrazine AT nilwannaboonlerd e112chlorophenylethylidene224dinitrophenylhydrazine AT jansrisewangwongpatcharaporn e112chlorophenylethylidene224dinitrophenylhydrazine AT kobkeatthawinthawanrat e112chlorophenylethylidene224dinitrophenylhydrazine AT funhoongkun e112chlorophenylethylidene224dinitrophenylhydrazine |