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1′,6-Dimethyl-4′-phenyl­dispiro­[1-benzopyran-3(4H),3′-pyrrolidine-2′,3′′-indoline]-2,2′′-dione

In the title compound, C(27)H(24)N(2)O(3), the five-membered pyrroldine ring adopts an envelope conformation (with the N atom in the flap position) and the six-membered pyran­one ring of the coumarine ring system adopts a slightly distorted boat conformation. The oxindole unit makes dihedral angles...

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Autores principales: Lakshmanan, D., Murugavel, S., Kannan, D., Bakthadoss, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239137/
https://www.ncbi.nlm.nih.gov/pubmed/22199985
http://dx.doi.org/10.1107/S1600536811050768
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author Lakshmanan, D.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
author_facet Lakshmanan, D.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
author_sort Lakshmanan, D.
collection PubMed
description In the title compound, C(27)H(24)N(2)O(3), the five-membered pyrroldine ring adopts an envelope conformation (with the N atom in the flap position) and the six-membered pyran­one ring of the coumarine ring system adopts a slightly distorted boat conformation. The oxindole unit makes dihedral angles of 89.7 (1) and 25.6 (1)°, respectively, with the pyrrolidine ring and the coumarin ring system. The mol­ecular structure is stabilized by two intra­molecular C—H⋯O contacts and two intra­molecular π–π inter­actions [centroid–centroid seperations of 3.514 (1) and 3.623 (1) Å]. The crystal packing features N—H⋯O hydrogen bonds, which link the mol­ecules into cyclic centrosymmetric R (2) (2)(8) dimers, and C—H⋯π inter­actions.
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spelling pubmed-32391372011-12-23 1′,6-Dimethyl-4′-phenyl­dispiro­[1-benzopyran-3(4H),3′-pyrrolidine-2′,3′′-indoline]-2,2′′-dione Lakshmanan, D. Murugavel, S. Kannan, D. Bakthadoss, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(24)N(2)O(3), the five-membered pyrroldine ring adopts an envelope conformation (with the N atom in the flap position) and the six-membered pyran­one ring of the coumarine ring system adopts a slightly distorted boat conformation. The oxindole unit makes dihedral angles of 89.7 (1) and 25.6 (1)°, respectively, with the pyrrolidine ring and the coumarin ring system. The mol­ecular structure is stabilized by two intra­molecular C—H⋯O contacts and two intra­molecular π–π inter­actions [centroid–centroid seperations of 3.514 (1) and 3.623 (1) Å]. The crystal packing features N—H⋯O hydrogen bonds, which link the mol­ecules into cyclic centrosymmetric R (2) (2)(8) dimers, and C—H⋯π inter­actions. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239137/ /pubmed/22199985 http://dx.doi.org/10.1107/S1600536811050768 Text en © Lakshmanan' et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lakshmanan, D.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
1′,6-Dimethyl-4′-phenyl­dispiro­[1-benzopyran-3(4H),3′-pyrrolidine-2′,3′′-indoline]-2,2′′-dione
title 1′,6-Dimethyl-4′-phenyl­dispiro­[1-benzopyran-3(4H),3′-pyrrolidine-2′,3′′-indoline]-2,2′′-dione
title_full 1′,6-Dimethyl-4′-phenyl­dispiro­[1-benzopyran-3(4H),3′-pyrrolidine-2′,3′′-indoline]-2,2′′-dione
title_fullStr 1′,6-Dimethyl-4′-phenyl­dispiro­[1-benzopyran-3(4H),3′-pyrrolidine-2′,3′′-indoline]-2,2′′-dione
title_full_unstemmed 1′,6-Dimethyl-4′-phenyl­dispiro­[1-benzopyran-3(4H),3′-pyrrolidine-2′,3′′-indoline]-2,2′′-dione
title_short 1′,6-Dimethyl-4′-phenyl­dispiro­[1-benzopyran-3(4H),3′-pyrrolidine-2′,3′′-indoline]-2,2′′-dione
title_sort 1′,6-dimethyl-4′-phenyl­dispiro­[1-benzopyran-3(4h),3′-pyrrolidine-2′,3′′-indoline]-2,2′′-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239137/
https://www.ncbi.nlm.nih.gov/pubmed/22199985
http://dx.doi.org/10.1107/S1600536811050768
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