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1-(4-Methyl­benz­yl)-2-(4-methyl­phen­yl)-1H-benzimidazole

The title compound, C(22)H(20)N(2), crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The benzimidazole units are almost planar [maximum deviations = 0.0161 (8) Å for A and 0.0276 (8) Å for B]. The dihedral angles between the benzimidazole unit and the benzene rings of t...

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Autores principales: Rosepriya, S., Thiruvalluvar, A., Jayamoorthy, K., Jayabharathi, J., Linden, Anthony
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239139/
https://www.ncbi.nlm.nih.gov/pubmed/22199987
http://dx.doi.org/10.1107/S160053681105077X
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author Rosepriya, S.
Thiruvalluvar, A.
Jayamoorthy, K.
Jayabharathi, J.
Linden, Anthony
author_facet Rosepriya, S.
Thiruvalluvar, A.
Jayamoorthy, K.
Jayabharathi, J.
Linden, Anthony
author_sort Rosepriya, S.
collection PubMed
description The title compound, C(22)H(20)N(2), crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The benzimidazole units are almost planar [maximum deviations = 0.0161 (8) Å for A and 0.0276 (8) Å for B]. The dihedral angles between the benzimidazole unit and the benzene rings of the 4-methyl­benzyl and 4-methyl­phenyl groups are 76.64 (3) and 46.87 (4)°, respectively, in mol­ecule A. The corresponding values in mol­ecule B are 86.31 (2) and 39.14 (4)°. The dihedral angles between the planes of the two benzene rings are 73.73 (3) and 80.69 (4)° in mol­ecules A and B, respectively. Pairs of weak inter­molecular C—H⋯N hydrogen bonds link B mol­ecules, forming centrosymmetric dimers with R (2) (2)(8) ring motifs. There are no significant corresponding inter­actions involving the A mol­ecules.
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spelling pubmed-32391392011-12-23 1-(4-Methyl­benz­yl)-2-(4-methyl­phen­yl)-1H-benzimidazole Rosepriya, S. Thiruvalluvar, A. Jayamoorthy, K. Jayabharathi, J. Linden, Anthony Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(20)N(2), crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The benzimidazole units are almost planar [maximum deviations = 0.0161 (8) Å for A and 0.0276 (8) Å for B]. The dihedral angles between the benzimidazole unit and the benzene rings of the 4-methyl­benzyl and 4-methyl­phenyl groups are 76.64 (3) and 46.87 (4)°, respectively, in mol­ecule A. The corresponding values in mol­ecule B are 86.31 (2) and 39.14 (4)°. The dihedral angles between the planes of the two benzene rings are 73.73 (3) and 80.69 (4)° in mol­ecules A and B, respectively. Pairs of weak inter­molecular C—H⋯N hydrogen bonds link B mol­ecules, forming centrosymmetric dimers with R (2) (2)(8) ring motifs. There are no significant corresponding inter­actions involving the A mol­ecules. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239139/ /pubmed/22199987 http://dx.doi.org/10.1107/S160053681105077X Text en © Rosepriya et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rosepriya, S.
Thiruvalluvar, A.
Jayamoorthy, K.
Jayabharathi, J.
Linden, Anthony
1-(4-Methyl­benz­yl)-2-(4-methyl­phen­yl)-1H-benzimidazole
title 1-(4-Methyl­benz­yl)-2-(4-methyl­phen­yl)-1H-benzimidazole
title_full 1-(4-Methyl­benz­yl)-2-(4-methyl­phen­yl)-1H-benzimidazole
title_fullStr 1-(4-Methyl­benz­yl)-2-(4-methyl­phen­yl)-1H-benzimidazole
title_full_unstemmed 1-(4-Methyl­benz­yl)-2-(4-methyl­phen­yl)-1H-benzimidazole
title_short 1-(4-Methyl­benz­yl)-2-(4-methyl­phen­yl)-1H-benzimidazole
title_sort 1-(4-methyl­benz­yl)-2-(4-methyl­phen­yl)-1h-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239139/
https://www.ncbi.nlm.nih.gov/pubmed/22199987
http://dx.doi.org/10.1107/S160053681105077X
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