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1-(4-Methylbenzyl)-2-(4-methylphenyl)-1H-benzimidazole
The title compound, C(22)H(20)N(2), crystallizes with two independent molecules (A and B) in the asymmetric unit. The benzimidazole units are almost planar [maximum deviations = 0.0161 (8) Å for A and 0.0276 (8) Å for B]. The dihedral angles between the benzimidazole unit and the benzene rings of t...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239139/ https://www.ncbi.nlm.nih.gov/pubmed/22199987 http://dx.doi.org/10.1107/S160053681105077X |
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author | Rosepriya, S. Thiruvalluvar, A. Jayamoorthy, K. Jayabharathi, J. Linden, Anthony |
author_facet | Rosepriya, S. Thiruvalluvar, A. Jayamoorthy, K. Jayabharathi, J. Linden, Anthony |
author_sort | Rosepriya, S. |
collection | PubMed |
description | The title compound, C(22)H(20)N(2), crystallizes with two independent molecules (A and B) in the asymmetric unit. The benzimidazole units are almost planar [maximum deviations = 0.0161 (8) Å for A and 0.0276 (8) Å for B]. The dihedral angles between the benzimidazole unit and the benzene rings of the 4-methylbenzyl and 4-methylphenyl groups are 76.64 (3) and 46.87 (4)°, respectively, in molecule A. The corresponding values in molecule B are 86.31 (2) and 39.14 (4)°. The dihedral angles between the planes of the two benzene rings are 73.73 (3) and 80.69 (4)° in molecules A and B, respectively. Pairs of weak intermolecular C—H⋯N hydrogen bonds link B molecules, forming centrosymmetric dimers with R (2) (2)(8) ring motifs. There are no significant corresponding interactions involving the A molecules. |
format | Online Article Text |
id | pubmed-3239139 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32391392011-12-23 1-(4-Methylbenzyl)-2-(4-methylphenyl)-1H-benzimidazole Rosepriya, S. Thiruvalluvar, A. Jayamoorthy, K. Jayabharathi, J. Linden, Anthony Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(20)N(2), crystallizes with two independent molecules (A and B) in the asymmetric unit. The benzimidazole units are almost planar [maximum deviations = 0.0161 (8) Å for A and 0.0276 (8) Å for B]. The dihedral angles between the benzimidazole unit and the benzene rings of the 4-methylbenzyl and 4-methylphenyl groups are 76.64 (3) and 46.87 (4)°, respectively, in molecule A. The corresponding values in molecule B are 86.31 (2) and 39.14 (4)°. The dihedral angles between the planes of the two benzene rings are 73.73 (3) and 80.69 (4)° in molecules A and B, respectively. Pairs of weak intermolecular C—H⋯N hydrogen bonds link B molecules, forming centrosymmetric dimers with R (2) (2)(8) ring motifs. There are no significant corresponding interactions involving the A molecules. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3239139/ /pubmed/22199987 http://dx.doi.org/10.1107/S160053681105077X Text en © Rosepriya et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rosepriya, S. Thiruvalluvar, A. Jayamoorthy, K. Jayabharathi, J. Linden, Anthony 1-(4-Methylbenzyl)-2-(4-methylphenyl)-1H-benzimidazole |
title | 1-(4-Methylbenzyl)-2-(4-methylphenyl)-1H-benzimidazole |
title_full | 1-(4-Methylbenzyl)-2-(4-methylphenyl)-1H-benzimidazole |
title_fullStr | 1-(4-Methylbenzyl)-2-(4-methylphenyl)-1H-benzimidazole |
title_full_unstemmed | 1-(4-Methylbenzyl)-2-(4-methylphenyl)-1H-benzimidazole |
title_short | 1-(4-Methylbenzyl)-2-(4-methylphenyl)-1H-benzimidazole |
title_sort | 1-(4-methylbenzyl)-2-(4-methylphenyl)-1h-benzimidazole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239139/ https://www.ncbi.nlm.nih.gov/pubmed/22199987 http://dx.doi.org/10.1107/S160053681105077X |
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