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Poly[[μ(2)-2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)](μ(2)-5-hydroxy­isophthalato-κ(2) O (1):O (3))zinc]

In the title coordination polymer, [Zn(C(8)H(4)O(5))(C(14)H(22)N(4))](n), the Zn(II) cation is coordinated by an O(2)N(2) donor set in a distorted tetra­hedral geometry. The Zn(II) ions are linked by μ(2)-OH-bdc (OH-H(2)bdc = 5-hy­droxy­isophthalic acid) and bbie ligands [bbie = 2,2′-diethyl-1,1′-(b...

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Detalles Bibliográficos
Autores principales: Liu, Ying-Ying, Wang, Xing, Yan, Yong-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246914/
https://www.ncbi.nlm.nih.gov/pubmed/22219734
http://dx.doi.org/10.1107/S1600536811039377
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author Liu, Ying-Ying
Wang, Xing
Yan, Yong-Sheng
author_facet Liu, Ying-Ying
Wang, Xing
Yan, Yong-Sheng
author_sort Liu, Ying-Ying
collection PubMed
description In the title coordination polymer, [Zn(C(8)H(4)O(5))(C(14)H(22)N(4))](n), the Zn(II) cation is coordinated by an O(2)N(2) donor set in a distorted tetra­hedral geometry. The Zn(II) ions are linked by μ(2)-OH-bdc (OH-H(2)bdc = 5-hy­droxy­isophthalic acid) and bbie ligands [bbie = 2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole], forming a two-dimensional layer parallel to the ab plane. The layers are further connected through intermolecular C—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional supramolecular structure. In the bbie ligand, the two C atoms in the ethyl group are each disordered over two positions with a site-occupancy ratio of 0.69:0.31.
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spelling pubmed-32469142012-01-04 Poly[[μ(2)-2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)](μ(2)-5-hydroxy­isophthalato-κ(2) O (1):O (3))zinc] Liu, Ying-Ying Wang, Xing Yan, Yong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Zn(C(8)H(4)O(5))(C(14)H(22)N(4))](n), the Zn(II) cation is coordinated by an O(2)N(2) donor set in a distorted tetra­hedral geometry. The Zn(II) ions are linked by μ(2)-OH-bdc (OH-H(2)bdc = 5-hy­droxy­isophthalic acid) and bbie ligands [bbie = 2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole], forming a two-dimensional layer parallel to the ab plane. The layers are further connected through intermolecular C—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional supramolecular structure. In the bbie ligand, the two C atoms in the ethyl group are each disordered over two positions with a site-occupancy ratio of 0.69:0.31. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246914/ /pubmed/22219734 http://dx.doi.org/10.1107/S1600536811039377 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ying-Ying
Wang, Xing
Yan, Yong-Sheng
Poly[[μ(2)-2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)](μ(2)-5-hydroxy­isophthalato-κ(2) O (1):O (3))zinc]
title Poly[[μ(2)-2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)](μ(2)-5-hydroxy­isophthalato-κ(2) O (1):O (3))zinc]
title_full Poly[[μ(2)-2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)](μ(2)-5-hydroxy­isophthalato-κ(2) O (1):O (3))zinc]
title_fullStr Poly[[μ(2)-2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)](μ(2)-5-hydroxy­isophthalato-κ(2) O (1):O (3))zinc]
title_full_unstemmed Poly[[μ(2)-2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)](μ(2)-5-hydroxy­isophthalato-κ(2) O (1):O (3))zinc]
title_short Poly[[μ(2)-2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)](μ(2)-5-hydroxy­isophthalato-κ(2) O (1):O (3))zinc]
title_sort poly[[μ(2)-2,2′-diethyl-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) n (3):n (3′)](μ(2)-5-hydroxy­isophthalato-κ(2) o (1):o (3))zinc]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246914/
https://www.ncbi.nlm.nih.gov/pubmed/22219734
http://dx.doi.org/10.1107/S1600536811039377
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