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catena-Poly[[[diaquamanganese(II)]-bis[μ-1,3-bis(1H-imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]] dinitrate]
In the title compound, {[Mn(C(14)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Mn(II) ion is located on an inversion center and is coordinated by four N atoms from four 1,3-bis(1H-imidazol-1-ylmethyl)benzene (L) ligands and two water molecules in a distorted octahedral geometry. Two L ligands are...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246916/ https://www.ncbi.nlm.nih.gov/pubmed/22219736 http://dx.doi.org/10.1107/S1600536811039882 |
| _version_ | 1782220003415687168 |
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| author | Wang, Xiao-Dan Hou, Guang-Feng Yu, Ying-Hui Gao, Jin-Sheng |
| author_facet | Wang, Xiao-Dan Hou, Guang-Feng Yu, Ying-Hui Gao, Jin-Sheng |
| author_sort | Wang, Xiao-Dan |
| collection | PubMed |
| description | In the title compound, {[Mn(C(14)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Mn(II) ion is located on an inversion center and is coordinated by four N atoms from four 1,3-bis(1H-imidazol-1-ylmethyl)benzene (L) ligands and two water molecules in a distorted octahedral geometry. Two L ligands are related by a centre of symmetry and bridge Mn(II) ions, forming a positively charged polymeric chain in [101]. Uncoordinated nitrate anions further link these chains into layers parallel to the ac plane via O—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3246916 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469162012-01-04 catena-Poly[[[diaquamanganese(II)]-bis[μ-1,3-bis(1H-imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]] dinitrate] Wang, Xiao-Dan Hou, Guang-Feng Yu, Ying-Hui Gao, Jin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Mn(C(14)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Mn(II) ion is located on an inversion center and is coordinated by four N atoms from four 1,3-bis(1H-imidazol-1-ylmethyl)benzene (L) ligands and two water molecules in a distorted octahedral geometry. Two L ligands are related by a centre of symmetry and bridge Mn(II) ions, forming a positively charged polymeric chain in [101]. Uncoordinated nitrate anions further link these chains into layers parallel to the ac plane via O—H⋯O hydrogen bonds. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246916/ /pubmed/22219736 http://dx.doi.org/10.1107/S1600536811039882 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Xiao-Dan Hou, Guang-Feng Yu, Ying-Hui Gao, Jin-Sheng catena-Poly[[[diaquamanganese(II)]-bis[μ-1,3-bis(1H-imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]] dinitrate] |
| title |
catena-Poly[[[diaquamanganese(II)]-bis[μ-1,3-bis(1H-imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]] dinitrate] |
| title_full |
catena-Poly[[[diaquamanganese(II)]-bis[μ-1,3-bis(1H-imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]] dinitrate] |
| title_fullStr |
catena-Poly[[[diaquamanganese(II)]-bis[μ-1,3-bis(1H-imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]] dinitrate] |
| title_full_unstemmed |
catena-Poly[[[diaquamanganese(II)]-bis[μ-1,3-bis(1H-imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]] dinitrate] |
| title_short |
catena-Poly[[[diaquamanganese(II)]-bis[μ-1,3-bis(1H-imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]] dinitrate] |
| title_sort | catena-poly[[[diaquamanganese(ii)]-bis[μ-1,3-bis(1h-imidazol-1-ylmethyl)benzene-κ(2)
n
(3):n
(3′)]] dinitrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246916/ https://www.ncbi.nlm.nih.gov/pubmed/22219736 http://dx.doi.org/10.1107/S1600536811039882 |
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