{2,2′-[o-Phenyl­enebis(nitrilo­methanylyl­idene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) monohydrate

The Ni(II) atom in the title monohydrate, [Ni(C(20)H(14)N(2)O(2))]·H(2)O, is coordinated within a cis-N(2)O(2) square-planar donor set provided by the tetra­dentate Schiff base ligand. Overall, the mol­ecule has a curved shape with the dihedral angle formed between the planes of the outer benzene ri...

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Detalles Bibliográficos
Autores principales: Ghaemi, Akbar, Fayyazi, Kazem, Keyvani, Bahram, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246917/
https://www.ncbi.nlm.nih.gov/pubmed/22219737
http://dx.doi.org/10.1107/S1600536811039730
Descripción
Sumario:The Ni(II) atom in the title monohydrate, [Ni(C(20)H(14)N(2)O(2))]·H(2)O, is coordinated within a cis-N(2)O(2) square-planar donor set provided by the tetra­dentate Schiff base ligand. Overall, the mol­ecule has a curved shape with the dihedral angle formed between the planes of the outer benzene rings being 13.92 (18)°. The water mol­ecule was found to be disordered over two positions [ratio 0.80 (1):0.20 (1)] and the major component is linked to the complex via an O—H⋯O hydrogen bond.

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