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Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis­(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate

In the crystal structure of the title complex, [Cr(3)(CH(3)CO(2))(6)(N(3))O(CH(3)OH)(2)]·CH(3)OH, the trinuclear core has a central O atom; two methanol mol­ecules and an azide ion are coordinated to the Cr(III) atoms in the core. The three Cr(III) atoms form vertices of a nearly equilateral triangl...

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Autores principales: Jiang, Guo-Qing, Li, Jian-Hua, Wang, Miao, Shi, Yu-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246918/
https://www.ncbi.nlm.nih.gov/pubmed/22219738
http://dx.doi.org/10.1107/S1600536811039699
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author Jiang, Guo-Qing
Li, Jian-Hua
Wang, Miao
Shi, Yu-Jun
author_facet Jiang, Guo-Qing
Li, Jian-Hua
Wang, Miao
Shi, Yu-Jun
author_sort Jiang, Guo-Qing
collection PubMed
description In the crystal structure of the title complex, [Cr(3)(CH(3)CO(2))(6)(N(3))O(CH(3)OH)(2)]·CH(3)OH, the trinuclear core has a central O atom; two methanol mol­ecules and an azide ion are coordinated to the Cr(III) atoms in the core. The three Cr(III) atoms form vertices of a nearly equilateral triangle. Each of the six acetate carboxyl­ate groups bridges a Cr—O—Cr fragment. In the crystal, the molecules inter­act with methanol solvent mol­ecules through O—H⋯O and O—H⋯N hydrogen bonds, forming a two-dimensional hydrogen-bonded network parallel to (100).
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spelling pubmed-32469182012-01-04 Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis­(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate Jiang, Guo-Qing Li, Jian-Hua Wang, Miao Shi, Yu-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Cr(3)(CH(3)CO(2))(6)(N(3))O(CH(3)OH)(2)]·CH(3)OH, the trinuclear core has a central O atom; two methanol mol­ecules and an azide ion are coordinated to the Cr(III) atoms in the core. The three Cr(III) atoms form vertices of a nearly equilateral triangle. Each of the six acetate carboxyl­ate groups bridges a Cr—O—Cr fragment. In the crystal, the molecules inter­act with methanol solvent mol­ecules through O—H⋯O and O—H⋯N hydrogen bonds, forming a two-dimensional hydrogen-bonded network parallel to (100). International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246918/ /pubmed/22219738 http://dx.doi.org/10.1107/S1600536811039699 Text en © Jiang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jiang, Guo-Qing
Li, Jian-Hua
Wang, Miao
Shi, Yu-Jun
Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis­(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate
title Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis­(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate
title_full Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis­(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate
title_fullStr Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis­(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate
title_full_unstemmed Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis­(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate
title_short Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis­(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate
title_sort hexa-μ(2)-acetato-κ(12) o:o′-(azido-κn)bis­(methanol-κo)-μ(3)-oxido-trichromium(iii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246918/
https://www.ncbi.nlm.nih.gov/pubmed/22219738
http://dx.doi.org/10.1107/S1600536811039699
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