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Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate
In the crystal structure of the title complex, [Cr(3)(CH(3)CO(2))(6)(N(3))O(CH(3)OH)(2)]·CH(3)OH, the trinuclear core has a central O atom; two methanol molecules and an azide ion are coordinated to the Cr(III) atoms in the core. The three Cr(III) atoms form vertices of a nearly equilateral triangl...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246918/ https://www.ncbi.nlm.nih.gov/pubmed/22219738 http://dx.doi.org/10.1107/S1600536811039699 |
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author | Jiang, Guo-Qing Li, Jian-Hua Wang, Miao Shi, Yu-Jun |
author_facet | Jiang, Guo-Qing Li, Jian-Hua Wang, Miao Shi, Yu-Jun |
author_sort | Jiang, Guo-Qing |
collection | PubMed |
description | In the crystal structure of the title complex, [Cr(3)(CH(3)CO(2))(6)(N(3))O(CH(3)OH)(2)]·CH(3)OH, the trinuclear core has a central O atom; two methanol molecules and an azide ion are coordinated to the Cr(III) atoms in the core. The three Cr(III) atoms form vertices of a nearly equilateral triangle. Each of the six acetate carboxylate groups bridges a Cr—O—Cr fragment. In the crystal, the molecules interact with methanol solvent molecules through O—H⋯O and O—H⋯N hydrogen bonds, forming a two-dimensional hydrogen-bonded network parallel to (100). |
format | Online Article Text |
id | pubmed-3246918 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32469182012-01-04 Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate Jiang, Guo-Qing Li, Jian-Hua Wang, Miao Shi, Yu-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Cr(3)(CH(3)CO(2))(6)(N(3))O(CH(3)OH)(2)]·CH(3)OH, the trinuclear core has a central O atom; two methanol molecules and an azide ion are coordinated to the Cr(III) atoms in the core. The three Cr(III) atoms form vertices of a nearly equilateral triangle. Each of the six acetate carboxylate groups bridges a Cr—O—Cr fragment. In the crystal, the molecules interact with methanol solvent molecules through O—H⋯O and O—H⋯N hydrogen bonds, forming a two-dimensional hydrogen-bonded network parallel to (100). International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246918/ /pubmed/22219738 http://dx.doi.org/10.1107/S1600536811039699 Text en © Jiang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jiang, Guo-Qing Li, Jian-Hua Wang, Miao Shi, Yu-Jun Hexa-μ(2)-acetato-κ(12) O:O′-(azido-κN)bis(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate |
title | Hexa-μ(2)-acetato-κ(12)
O:O′-(azido-κN)bis(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate |
title_full | Hexa-μ(2)-acetato-κ(12)
O:O′-(azido-κN)bis(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate |
title_fullStr | Hexa-μ(2)-acetato-κ(12)
O:O′-(azido-κN)bis(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate |
title_full_unstemmed | Hexa-μ(2)-acetato-κ(12)
O:O′-(azido-κN)bis(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate |
title_short | Hexa-μ(2)-acetato-κ(12)
O:O′-(azido-κN)bis(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate |
title_sort | hexa-μ(2)-acetato-κ(12)
o:o′-(azido-κn)bis(methanol-κo)-μ(3)-oxido-trichromium(iii) methanol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246918/ https://www.ncbi.nlm.nih.gov/pubmed/22219738 http://dx.doi.org/10.1107/S1600536811039699 |
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